Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

S Rej, A Das, N Chatani - Coordination Chemistry Reviews, 2021 - Elsevier
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

[HTML][HTML] Decarboxylative reactions with and without light–a comparison

J Schwarz, B König - Green Chemistry, 2018 - pubs.rsc.org
Carboxylic acids have gained more and more importance as versatile and renewable
starting materials for the formation of platform molecules or high-value chemicals. Many …

A unified approach to decarboxylative halogenation of (hetero) aryl carboxylic acids

TQ Chen, PS Pedersen, NW Dow… - Journal of the …, 2022 - ACS Publications
Aryl halides are a fundamental motif in synthetic chemistry, playing a critical role in metal-
mediated cross-coupling reactions and serving as important scaffolds in drug discovery …

What does nanoparticle stability mean?

HT Phan, AJ Haes - The Journal of Physical Chemistry C, 2019 - ACS Publications
The term “nanoparticle stability” is widely used to describe the preservation of a particular
nanostructure property ranging from aggregation, composition, crystallinity, shape, size, and …

Recent advances in transition-metal-catalyzed functionalization of unstrained carbon–carbon bonds

F Chen, T Wang, N Jiao - Chemical Reviews, 2014 - ACS Publications
The carbon− carbon bond is the most widespread and fundamental bond existing in organic
compounds. The reaction of this kind of bond is almost ubiquitous in live activities and …

Decarboxylative coupling reactions: a modern strategy for C–C-bond formation

N Rodríguez, LJ Goossen - Chemical Society Reviews, 2011 - pubs.rsc.org
This critical review examines transition metal-catalyzed decarboxylative couplings that have
emerged within recent years as a powerful strategy to form carbon–carbon or carbon …

Hydrodecarboxylation of carboxylic and malonic acid derivatives via organic photoredox catalysis: substrate scope and mechanistic insight

JD Griffin, MA Zeller, DA Nicewicz - Journal of the American …, 2015 - ACS Publications
A direct, catalytic hydrodecarboxylation of primary, secondary, and tertiary carboxylic acids
is reported. The catalytic system consists of a Fukuzumi acridinium photooxidant with …

Carboxylic acids as substrates in homogeneous catalysis

LJ Gooßen, N Rodríguez… - Angewandte Chemie …, 2008 - Wiley Online Library
In organic molecules carboxylic acid groups are among the most common functionalities.
Activated derivatives of carboxylic acids have long served as versatile connection points in …

Chemoselective Decarboxylative Protonation Enabled by Cooperative Earth‐Abundant Element Catalysis

YC Lu, JG West - Angewandte Chemie, 2023 - Wiley Online Library
Decarboxylative protonation is a general deletion tactic to replace polar carboxylic acid
groups with hydrogen or its isotope. Current methods rely on the pre‐activation of acids, non …

The use of carboxylic acids as traceless directing groups for regioselective C–H bond functionalisation

M Font, JM Quibell, GJP Perry, I Larrosa - Chemical Communications, 2017 - pubs.rsc.org
The ability to selectively functionalise a specific C–H bond is a long-standing challenge due
to the ubiquity of such bonds in organic molecules. One of the most common approaches to …