Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …
[HTML][HTML] Decarboxylative reactions with and without light–a comparison
J Schwarz, B König - Green Chemistry, 2018 - pubs.rsc.org
Carboxylic acids have gained more and more importance as versatile and renewable
starting materials for the formation of platform molecules or high-value chemicals. Many …
starting materials for the formation of platform molecules or high-value chemicals. Many …
A unified approach to decarboxylative halogenation of (hetero) aryl carboxylic acids
TQ Chen, PS Pedersen, NW Dow… - Journal of the …, 2022 - ACS Publications
Aryl halides are a fundamental motif in synthetic chemistry, playing a critical role in metal-
mediated cross-coupling reactions and serving as important scaffolds in drug discovery …
mediated cross-coupling reactions and serving as important scaffolds in drug discovery …
What does nanoparticle stability mean?
The term “nanoparticle stability” is widely used to describe the preservation of a particular
nanostructure property ranging from aggregation, composition, crystallinity, shape, size, and …
nanostructure property ranging from aggregation, composition, crystallinity, shape, size, and …
Recent advances in transition-metal-catalyzed functionalization of unstrained carbon–carbon bonds
The carbon− carbon bond is the most widespread and fundamental bond existing in organic
compounds. The reaction of this kind of bond is almost ubiquitous in live activities and …
compounds. The reaction of this kind of bond is almost ubiquitous in live activities and …
Decarboxylative coupling reactions: a modern strategy for C–C-bond formation
N Rodríguez, LJ Goossen - Chemical Society Reviews, 2011 - pubs.rsc.org
This critical review examines transition metal-catalyzed decarboxylative couplings that have
emerged within recent years as a powerful strategy to form carbon–carbon or carbon …
emerged within recent years as a powerful strategy to form carbon–carbon or carbon …
Hydrodecarboxylation of carboxylic and malonic acid derivatives via organic photoredox catalysis: substrate scope and mechanistic insight
JD Griffin, MA Zeller, DA Nicewicz - Journal of the American …, 2015 - ACS Publications
A direct, catalytic hydrodecarboxylation of primary, secondary, and tertiary carboxylic acids
is reported. The catalytic system consists of a Fukuzumi acridinium photooxidant with …
is reported. The catalytic system consists of a Fukuzumi acridinium photooxidant with …
Carboxylic acids as substrates in homogeneous catalysis
LJ Gooßen, N Rodríguez… - Angewandte Chemie …, 2008 - Wiley Online Library
In organic molecules carboxylic acid groups are among the most common functionalities.
Activated derivatives of carboxylic acids have long served as versatile connection points in …
Activated derivatives of carboxylic acids have long served as versatile connection points in …
Chemoselective Decarboxylative Protonation Enabled by Cooperative Earth‐Abundant Element Catalysis
Decarboxylative protonation is a general deletion tactic to replace polar carboxylic acid
groups with hydrogen or its isotope. Current methods rely on the pre‐activation of acids, non …
groups with hydrogen or its isotope. Current methods rely on the pre‐activation of acids, non …
The use of carboxylic acids as traceless directing groups for regioselective C–H bond functionalisation
The ability to selectively functionalise a specific C–H bond is a long-standing challenge due
to the ubiquity of such bonds in organic molecules. One of the most common approaches to …
to the ubiquity of such bonds in organic molecules. One of the most common approaches to …