Microstructural and dynamical heterogeneities in ionic liquids

YL Wang, B Li, S Sarman, F Mocci, ZY Lu… - Chemical …, 2020 - ACS Publications
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …

Solvents and sustainable chemistry

T Welton - Proceedings of the Royal Society A …, 2015 - royalsocietypublishing.org
Solvents are widely recognized to be of great environmental concern. The reduction of their
use is one of the most important aims of green chemistry. In addition to this, the appropriate …

[PDF][PDF] 离子液体与绿色化学

张锁江, 徐春明, 吕兴梅 - 2009 - ecsponline.com
离子液体是国际绿色化学的前沿和热点. 本书以离子液体和绿色化学的前沿科学研究为主线,
系统介绍离子液体在绿色化学方面的最新研究成果和进展, 包括离子液体的结构与性质关系以及 …

OH stretching and libration bands of solitary water in ionic liquids and dipolar solvents share a single dependence on solvent polarity

K Mukherjee, S Palchowdhury… - The Journal of Physical …, 2022 - ACS Publications
Ionic liquids are an emerging class of materials which are finding application in a variety of
technologically important areas. Because of their hydrophilic character, at least a small …

Water Nanocluster Formation in the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate ([C4mim][BF4])–D2O Mixtures

J Gao, NJ Wagner - Langmuir, 2016 - ACS Publications
The microstructure of mixtures of deuterated water in the ionic liquid [C4mim][BF4] is
investigated by small-angle neutron scattering (SANS) measurement. In the salt-rich region …

Effect of the cation on the interactions between alkyl methyl imidazolium chloride ionic liquids and water

I Khan, M Taha, P Ribeiro-Claro, SP Pinho… - The Journal of …, 2014 - ACS Publications
A systematic study of the interactions between water and alkyl methyl imidazolium chloride
ionic liquids at 298.2 K, based on activity coefficients estimated from water activity …

Sifting ionic liquids as additives for separation of acetonitrile and water azeotropic mixture using the COSMO-RS method

J Li, X Yang, K Chen, Y Zheng, C Peng… - Industrial & engineering …, 2012 - ACS Publications
The phase behavior of the ternary acetonitrile+ water+ ionic liquid system was predicted
using the COSMO-RS method. The effects of different ionic liquids on the separation of …

[HTML][HTML] A FT-IR spectroscopic study of ultrasound effect on aqueous imidazole based ionic liquids having different counter ions

K Li, T Kobayashi - Ultrasonics Sonochemistry, 2016 - Elsevier
Abstract Ultrasound (US) effect on 1-butyl-3-methyl-imidazolium (BMI) ionic liquids having
different counter anions, BF 4−, PF 6− and Cl− in aqueous medium was studied by FT-IR …

Separation of 2-propanol and water azeotropic system using ionic liquids as entrainers

Z Zhang, L Zhang, Q Zhang, D Sun, F Pan, S Dai… - Fluid Phase Equilibria, 2016 - Elsevier
propanol and water form an azeotropic mixture of the minimum boiling point at constant
pressure. In this work, three ionic liquids (ILs), namely 1-ethyl-3-methylimidazolium acetate …

Interfacial water and microheterogeneity in aqueous solutions of ionic liquids

C Bottari, L Almásy, B Rossi, B Bracco… - The Journal of …, 2022 - ACS Publications
In this work, aqueous solutions of two prototypical ionic liquids (ILs),[BMIM][BF4] and
[BMIM][TfO], were investigated by UV Raman spectroscopy and small-angle neutron …