Defects in the self-assembly of block copolymers and their relevance for directed self-assembly

W Li, M Müller - Annual review of chemical and biomolecular …, 2015 - annualreviews.org
Block copolymer self-assembly provides a platform for fabricating dense, ordered
nanostructures by encoding information in the chemical architecture of multicomponent …

Symmetry-breaking and self-sorting in block copolymer-based multicomponent nanocomposites

L Ma, H Huang, P Ercius, A Alexander-Katz, T Xu - ACS nano, 2022 - ACS Publications
Co-assembly of inorganic nanoparticles (NPs) and nanostructured polymer matrix
represents an intricate interplay of enthalpic or entropic forces. Particle size largely affects …

Strong ligand–block copolymer interactions for incorporation of relatively large nanoparticles in ordered composites

Y Gai, Y Lin, DP Song, BM Yavitt, JJ Watkins - Macromolecules, 2016 - ACS Publications
For well-ordered block copolymer (BCP) nanocomposites containing nanoparticles (NPs),
the ratio of NP core diameter (d core) and BCP domain width (L) has been generally limited …

Equilibrium field theoretic study of nanoparticle interactions in diblock copolymer melts

BJ Lindsay, RJ Composto… - The Journal of Physical …, 2019 - ACS Publications
Block copolymer matrices are often used to control nanoparticle (NP) dispersion behavior,
but the effects of diblock domain interfaces on particle–particle interactions have not been …

Simulation and Fabrication of Nanoscale Spirals Based on Dual-Scale Self-Assemblies

GH Lee, S Kim, YJ Kim, MS Jang… - ACS Applied Materials & …, 2020 - ACS Publications
Archimedean spirals in nanometer scale have shown remarkable plasmonic responses
derived from their linear and rotational asymmetry. Despite the unique optical properties of …

Individual confinement of block copolymer microdomains in nanoscale crossbar templates

WI Park, YK Jung, YJ Kim, WH Shin… - Advanced Functional …, 2019 - Wiley Online Library
Highly ordered pattern formation of block copolymers (BCPs) within nanoscale templates is
of great interest for generating diverse ordered nanostructures. Here, introduced is a …

Field-theoretic simulations of the distribution of nanorods in diblock copolymer thin films

H Chao, BJ Lindsay, RA Riggleman - The Journal of Physical …, 2017 - ACS Publications
Using block copolymer microphases to guide the self-assembly of nanorods in thin films can
give rise to polymeric materials with unique optical, thermal, and mechanical properties …

Attraction of nanoparticles to tilt grain boundaries in block copolymers

J Koski, B Hagberg… - … Chemistry and Physics, 2016 - Wiley Online Library
Self‐assembly of block copolymers can be used to create nanoscale patterns for numerous
applications that span from the fabrication of microelectronic devices to producing structured …

Customizing topographical templates for aperiodic nanostructures of block copolymers via inverse design

R Zhang, L Zhang, J Lin, S Lin - Physical Chemistry Chemical Physics, 2019 - pubs.rsc.org
The limited complexity of self-assembled nanostructures of block copolymers seriously
impedes their potential utility in the semiconductor industry. Therefore, the customizability of …

Coarse-Grained Modeling of Polymer Nanocomposites: Field-Theoretic Simulations

JP Koski, H Chao, C Tabedzki… - Theory and Modeling of …, 2021 - Springer
For several decades polymer field theory has been an important computational and
theoretical tool for predicting and interpreting the phase behavior of polymers. Many …