Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
A guide to secondary coordination sphere editing
MW Drover - Chemical Society Reviews, 2022 - pubs.rsc.org
This tutorial review showcases recent (2015–2021) work describing ligand construction as it
relates to the design of secondary coordination spheres (SCSs). Metalloenzymes, for …
relates to the design of secondary coordination spheres (SCSs). Metalloenzymes, for …
Unlocking the transition of electrochemical water oxidation mechanism induced by heteroatom doping
X Li, C Deng, Y Kong, Q Huo, L Mi… - Angewandte Chemie …, 2023 - Wiley Online Library
Heteroatom doping has emerged as a highly effective strategy to enhance the activity of
metal‐based electrocatalysts toward the oxygen evolution reaction (OER). It is widely …
metal‐based electrocatalysts toward the oxygen evolution reaction (OER). It is widely …
High Configuration Entropy Activated Lattice Oxygen for O2 Formation on Perovskite Electrocatalyst
L Tang, Y Yang, H Guo, Y Wang… - Advanced Functional …, 2022 - Wiley Online Library
The single‐phase oxides with elemental complexity and compositional diversity, usually
named high entropy oxides, feature homogeneously dispersed multi‐metallic elements in …
named high entropy oxides, feature homogeneously dispersed multi‐metallic elements in …
Proton-coupled electron transfer guidelines, fair and square
Proton-coupled electron transfer (PCET) reactions are fundamental to energy transformation
reactions in natural and artificial systems and are increasingly recognized in areas such as …
reactions in natural and artificial systems and are increasingly recognized in areas such as …
Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts
The oxygen evolution reaction (OER) is a key process in electrochemical energy conversion
devices. Understanding the origins of the lattice oxygen oxidation mechanism is crucial …
devices. Understanding the origins of the lattice oxygen oxidation mechanism is crucial …
Accessing photoredox transformations with an iron (III) photosensitizer and green light
A Aydogan, RE Bangle, A Cadranel… - Journal of the …, 2021 - ACS Publications
Efficient excited-state electron transfer between an iron (III) photosensitizer and organic
electron donors was realized with green light irradiation. This advance was enabled by the …
electron donors was realized with green light irradiation. This advance was enabled by the …
Regulation of the electrocatalytic nitrogen cycle based on sequential proton–electron transfer
The selective transformation of nitrogen compounds is a foundation of the modern chemical
industry. Existing thermochemical processes largely rely on fossil fuels and innovating …
industry. Existing thermochemical processes largely rely on fossil fuels and innovating …
Efficient O–O coupling at catalytic interface to assist kinetics optimization on concerted and sequential proton–electron transfer for water oxidation
A catalyst kinetics optimization strategy based on tuning active site intermediates adsorption
is proposed. Construction of the M-OOH on the catalytic site before the rate-determining step …
is proposed. Construction of the M-OOH on the catalytic site before the rate-determining step …
Tuning proton-coupled electron transfer by crystal orientation for efficient water oxidization on double perovskite oxides
Developing highly efficient and cost-effective oxygen evolution reaction (OER)
electrocatalysts is critical for many energy devices. While regulating the proton-coupled …
electrocatalysts is critical for many energy devices. While regulating the proton-coupled …