Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis

PRD Murray, JH Cox, ND Chiappini, CB Roos… - Chemical …, 2021 - ACS Publications
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

A guide to secondary coordination sphere editing

MW Drover - Chemical Society Reviews, 2022 - pubs.rsc.org
This tutorial review showcases recent (2015–2021) work describing ligand construction as it
relates to the design of secondary coordination spheres (SCSs). Metalloenzymes, for …

Unlocking the transition of electrochemical water oxidation mechanism induced by heteroatom doping

X Li, C Deng, Y Kong, Q Huo, L Mi… - Angewandte Chemie …, 2023 - Wiley Online Library
Heteroatom doping has emerged as a highly effective strategy to enhance the activity of
metal‐based electrocatalysts toward the oxygen evolution reaction (OER). It is widely …

High Configuration Entropy Activated Lattice Oxygen for O2 Formation on Perovskite Electrocatalyst

L Tang, Y Yang, H Guo, Y Wang… - Advanced Functional …, 2022 - Wiley Online Library
The single‐phase oxides with elemental complexity and compositional diversity, usually
named high entropy oxides, feature homogeneously dispersed multi‐metallic elements in …

Proton-coupled electron transfer guidelines, fair and square

R Tyburski, T Liu, SD Glover… - Journal of the American …, 2021 - ACS Publications
Proton-coupled electron transfer (PCET) reactions are fundamental to energy transformation
reactions in natural and artificial systems and are increasingly recognized in areas such as …

Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts

ZF Huang, J Song, Y Du, S Xi, S Dou… - Nature Energy, 2019 - nature.com
The oxygen evolution reaction (OER) is a key process in electrochemical energy conversion
devices. Understanding the origins of the lattice oxygen oxidation mechanism is crucial …

Accessing photoredox transformations with an iron (III) photosensitizer and green light

A Aydogan, RE Bangle, A Cadranel… - Journal of the …, 2021 - ACS Publications
Efficient excited-state electron transfer between an iron (III) photosensitizer and organic
electron donors was realized with green light irradiation. This advance was enabled by the …

Regulation of the electrocatalytic nitrogen cycle based on sequential proton–electron transfer

D He, H Ooka, Y Li, Y Kim, A Yamaguchi, K Adachi… - Nature Catalysis, 2022 - nature.com
The selective transformation of nitrogen compounds is a foundation of the modern chemical
industry. Existing thermochemical processes largely rely on fossil fuels and innovating …

Efficient O–O coupling at catalytic interface to assist kinetics optimization on concerted and sequential proton–electron transfer for water oxidation

C Qiao, Z Usman, J Wei, L Gan, J Hou, Y Hao, Y Zhu… - ACS …, 2023 - ACS Publications
A catalyst kinetics optimization strategy based on tuning active site intermediates adsorption
is proposed. Construction of the M-OOH on the catalytic site before the rate-determining step …

Tuning proton-coupled electron transfer by crystal orientation for efficient water oxidization on double perovskite oxides

Y Zhu, Z He, YM Choi, H Chen, X Li, B Zhao… - Nature …, 2020 - nature.com
Developing highly efficient and cost-effective oxygen evolution reaction (OER)
electrocatalysts is critical for many energy devices. While regulating the proton-coupled …