[HTML][HTML] Proton transfer reactions: from photochemistry to biochemistry and bioenergetics

AP Demchenko - BBA advances, 2023 - Elsevier
The present Review is an attempt by projecting the basic knowledge on photochemical
proton transfer to achieve consistent understanding of proton motions in biocatalysis …

[HTML][HTML] Nonequilibrium thermodynamics in biochemical systems and its application

D Zhang, Q Ouyang - Entropy, 2021 - mdpi.com
Living systems are open systems, where the laws of nonequilibrium thermodynamics play
the important role. Therefore, studying living systems from a nonequilibrium thermodynamic …

Conservatively Perturbed Equilibrium (CPE) in chemical kinetics

GS Yablonsky, PD Branco, GB Marin… - Chemical Engineering …, 2019 - Elsevier
Abstract The phenomenon of “Conservatively Perturbed Equilibrium”(CPE) in chemical
kinetics is distinguished using a sequence of first-order reactions (linear mechanism) and …

New invariances for chemical reactions from Scaled Incremental Conversion (SIC)

PD Branco, GS Yablonsky, GB Marin… - Chemical Engineering …, 2018 - Elsevier
For the two-step chemical reaction A⇄ B⇄ C, invariant dependences of a new type have
been found. These invariants relate concentration dependences which are started from the …

Joint kinetics: A new paradigm for chemical kinetics and chemical engineering

GS Yablonsky, D Constales, GB Marin - Current Opinion in Chemical …, 2020 - Elsevier
Joint kinetics, a new paradigm for chemical kinetics and chemical engineering, is proposed.
Its main idea is performing a battery of kinetic experiments from special initial compositions …

Invariant expressions for linear complex mechanisms: Generalization for polar two-step sub-mechanisms

D Branco, GS Yablonsky, GB Marin… - Chemical Engineering …, 2020 - Elsevier
We generalize the results on invariances found for linear two-step mechanism within our
approach to joint kinetics. It is demonstrated that similar invariances can be formulated for …

[HTML][HTML] A robust method for the estimation of kinetic parameters for systems including slow and rapid reactions—From differential-algebraic model to differential …

T Salmi, E Tirronen, J Wärnå, JP Mikkola, D Murzin… - Processes, 2020 - mdpi.com
Reliable estimation of kinetic parameters in chemical systems comprising both slow and
rapid reaction steps and rapidly reacting intermediate species is a difficult differential …

Swapping the equilibrium

GS Yablonsky, D Branco, GB Marin… - Chemical Engineering …, 2019 - Elsevier
Abstract A “swapped equilibrium”(SE) occurs when the initial concentrations of two chemical
species are taken as their equilibrium concentrations, but swapped. In complex …

Estudo térmico, vibracional e cálculos teóricos em cristais de l-tirosina e haletos em altas temperaturas e altas pressões

CAAS SANTOS - 2023 - tedebc.ufma.br
Esta tese se propôs a sintetizar e a caracterizar de forma estrutural, térmica e vibracional
cristais da L-tirosina (LT) e seus haletos e um fazer um estudo comparativo entre eles …

[PDF][PDF] BBA Advances

AP Demchenko - scienceopen.com
The present Review is an attempt by projecting the basic knowledge on photochemical
proton transfer to achieve consistent understanding of proton motions in biocatalysis …