Nuclear quantum effects in water and aqueous systems: Experiment, theory, and current challenges

M Ceriotti, W Fang, PG Kusalik, RH McKenzie… - Chemical …, 2016 - ACS Publications
Nuclear quantum effects influence the structure and dynamics of hydrogen-bonded systems,
such as water, which impacts their observed properties with widely varying magnitudes. This …

[HTML][HTML] The structural origin of anomalous properties of liquid water

A Nilsson, LGM Pettersson - Nature communications, 2015 - nature.com
Water is unique in its number of unusual, often called anomalous, properties. When hot it is
a normal simple liquid; however, close to ambient temperatures properties, such as the …

The structure of interfacial water on gold electrodes studied by x-ray absorption spectroscopy

JJ Velasco-Velez, CH Wu, TA Pascal, LF Wan, J Guo… - Science, 2014 - science.org
The molecular structure of the electrical double layer determines the chemistry in all
electrochemical processes. Using x-ray absorption spectroscopy (XAS), we probed the …

Water: A tale of two liquids

P Gallo, K Amann-Winkel, CA Angell… - Chemical …, 2016 - ACS Publications
Water is the most abundant liquid on earth and also the substance with the largest number
of anomalies in its properties. It is a prerequisite for life and as such a most important subject …

Ultrahigh density of gas molecules confined in surface nanobubbles in ambient water

L Zhou, X Wang, HJ Shin, J Wang, R Tai… - Journal of the …, 2020 - ACS Publications
To understand the unexpected and puzzling long-term stability of nanoscale gas bubbles, it
is crucial to probe their nature and intrinsic properties. We report herein synchrotron-based …

Perspective on the structure of liquid water

A Nilsson, LGM Pettersson - Chemical Physics, 2011 - Elsevier
We present a picture that combines discussions regarding the thermodynamic anomalies in
ambient and supercooled water with recent interpretations of X-ray spectroscopy and …

X-ray and electron spectroscopy of water

T Fransson, Y Harada, N Kosugi, NA Besley… - Chemical …, 2016 - ACS Publications
Here we present an overview of recent developments of X-ray and electron spectroscopy to
probe water at different temperatures. Photon-induced ionization followed by detection of …

Soft x-ray absorption spectroscopy of liquids and solutions

JW Smith, RJ Saykally - Chemical reviews, 2017 - ACS Publications
X-ray absorption spectroscopy (XAS) is an electronic absorption technique for which the
initial state is a deeply buried core level. The photon energies corresponding to such …

From local covalent bonding to extended electric field interactions in proton hydration

M Ekimova, C Kleine, J Ludwig… - Angewandte Chemie …, 2022 - Wiley Online Library
Seemingly simple yet surprisingly difficult to probe, excess protons in water constitute
complex quantum objects with strong interactions with the extended and dynamically …

Electrolytes induce long-range orientational order and free energy changes in the H-bond network of bulk water

Y Chen, HI Okur, N Gomopoulos, C Macias-Romero… - Science …, 2016 - science.org
Electrolytes interact with water in many ways: changing dipole orientation, inducing charge
transfer, and distorting the hydrogen-bond network in the bulk and at interfaces. Numerous …