New advances in using Raman spectroscopy for the characterization of catalysts and catalytic reactions

C Hess - Chemical Society Reviews, 2021 - pubs.rsc.org
Gaining insight into the mode of operation of heterogeneous catalysts is of great scientific
and economic interest. Raman spectroscopy has proven its potential as a powerful …

Restructuring effects of the chemical environment in metal nanocatalysis and single-atom catalysis

L Piccolo - Catalysis Today, 2021 - Elsevier
Metal-based heterogeneous catalysts mostly consist of supported nanoparticles of a few
nanometers in size, since these objects provide a good compromise between exposed …

Pt atomic single-layer catalyst embedded in defect-enriched ceria for efficient CO oxidation

S Xie, L Liu, Y Lu, C Wang, S Cao, W Diao… - Journal of the …, 2022 - ACS Publications
The local coordination structure of metal sites essentially determines the performance of
supported metal catalysts. Using a surface defect enrichment strategy, we successfully …

Raman Spectra of Polycrystalline CeO2: A Density Functional Theory Study

C Schilling, A Hofmann, C Hess… - The Journal of …, 2017 - ACS Publications
Cerium oxide is an important material for catalytic and fuel cell applications. We present an
ab initio density functional theory (DFT) study of the vibrational properties of ceria focusing …

Shape effect of Pt/CeO2 catalysts on the catalytic oxidation of toluene

R Peng, X Sun, S Li, L Chen, M Fu, J Wu… - Chemical Engineering …, 2016 - Elsevier
The present work elucidated the shape effect of Pt/CeO 2 catalysts toward catalytic oxidation
of toluene. CeO 2 nanorods, nanoparticles, and nanocubes, dominantly exposed {1 1 0},{1 1 …

Raman spectroscopy as a powerful tool to characterize ceria-based catalysts

S Loridant - Catalysis Today, 2021 - Elsevier
A review. CeO 2 is widely used and investigated as an oxide catalyst or support due to its
unique redox property of oxygen storage and release. In this paper, the different …

Ni/CeO2 based catalysts as oxygen vectors for the chemical looping dry reforming of methane for syngas production

A Löfberg, J Guerrero-Caballero, T Kane… - Applied Catalysis B …, 2017 - Elsevier
Chemical looping dry reforming of methane (CLDRM) is performed by exposing a Ni/CeO 2
solid to CH 4 and CO 2 in a cyclic way. The solid acts as an oxygen vector producing syngas …

How Pt interacts with CeO2 under the reducing and oxidizing environments at elevated temperature: the origin of improved thermal stability of Pt/CeO2 compared to …

J Lee, YS Ryou, X Chan, TJ Kim… - The Journal of Physical …, 2016 - ACS Publications
The interaction between Pt and CeO2 under reducing and oxidizing conditions as well as its
effect on the thermal stability of Pt/CeO2 were extensively investigated by means of N2 …

Boosting the Removal of Diesel Soot Particles by the Optimal Exposed Crystal Facet of CeO2 in Au/CeO2 Catalysts

Y Wei, Y Zhang, P Zhang, J Xiong, X Mei… - Environmental …, 2019 - ACS Publications
Optimized surface facet of the catalysts is an efficient strategy to boost catalytic purification of
diesel soot as important components of atmospheric fine particles. Herein, we have …

Catalytic combustion of chlorinated aromatics over WOx/CeO2 catalysts at low temperature

Y Gu, T Cai, X Gao, H Xia, W Sun, J Zhao, Q Dai… - Applied Catalysis B …, 2019 - Elsevier
WO x/CeO 2 catalysts prepared by wet impregnation with (NH 4) 6 H 2 W 12 O 40 and
(COOH) 2 aqueous solution were used in the catalytic combustion of chlorobenzene (CB) …