A mononuclear and dinuclear rhenium tricarbonyl compounds were synthesized by the one-
pot condensation reaction of [Re (CO) 5 Br], pyrrole-2-carboxaldehyde and 4‑chloro-m …

We applied a test set of ligand dissociation enthalpies derived entirely from a unified
experimental approach to evaluate the efficacy of various methods for modeling …

The reaction of a bidentate pyrrole based rhenium tetracarbonyl complex with
dimethylamine borane at room temperature results in rapid dehydrogenation. Hydrogen …

The synthesis, structure and CO-releasing properties of a number of new tricarbonyl
rhenium (I) complexes with 5-substituted-6-amino-1, 3-dimethyluracils are reported and their …

Dissolution of M (CO) 3 (Br)(LAr)[LAr=(2, 6-Cl2-C6H3-NCMe) 2CH2] in either acetonitrile
[M= Mn, Re] or benzonitrile (M= Re) results in C–C coupling of the nitrile to the diimine …

Abstract Kryptopyrrole (2, 4‐dimethyl‐3‐ethylpyrrole) was acylated with, for example,
benzoyl chloride to afford 2‐benzoyl‐3, 5‐dimethyl‐4‐ethylpyrrole (L1H). With SiCl4 this …

Neutral phosphine oxide (PO) donor-based organometallic complexes [{Re (CO) 3OPCy3}{μ-
DHBQ}{Re (CO) 3OPCy3}](1),[{Re (CO) 3OPPh3}{μ-DHBQ}{Re (CO) 3OPPh3}](2),[{Re (CO) …

With the goal of generating anionic analogues to MN2S2⋅ Mn (CO) 3Br we introduced
metallodithiolate ligands, MN2S22− prepared from the Cys‐X‐Cys biomimetic, ema4 …

A molecular, porous crystalline material constructed from neutral helical coordination
polymers incorporating manganese (II) ions and two types of bridging ligands, namely the …

This work aims to extend the coordination chemistry of Co (II) with bis (2-formylpyrrolyl)
ligands to different donor molecules. Treatment of a mixture of anhydrous CoCl 2 and …