Programmable and adaptive mechanics with liquid crystal polymer networks and elastomers

TJ White, DJ Broer - Nature materials, 2015 - nature.com
Liquid crystals are the basis of a pervasive technology of the modern era. Yet, as the display
market becomes commoditized, researchers in industry, government and academia are …

Photochromism of diarylethene molecules and crystals: memories, switches, and actuators

M Irie, T Fukaminato, K Matsuda, S Kobatake - Chemical Reviews, 2014 - ACS Publications
Photochromism is defined as a reversible transformation of a chemical species between two
isomers having different absorption spectra induced in one or both directions by …

Polymer mechanochromism from force-tuned excited-state intramolecular proton transfer

H Hu, X Cheng, Z Ma, RP Sijbesma… - Journal of the American …, 2022 - ACS Publications
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …

[HTML][HTML] Mechanically responsive molecular crystals

P Naumov, S Chizhik, MK Panda, NK Nath… - Chemical …, 2015 - ACS Publications
Transformation of energy into motion (work) is one of the basic processes of energy
conversion in nature. The processes of actuation underlying the transduction of light …

[HTML][HTML] Directed bending of a polymer film by light

Y Yu, M Nakano, T Ikeda - Nature, 2003 - nature.com
Polymer solutions and solids that contain light-sensitive molecules can undergo photo-
contraction, whereby light energy is converted into mechanical energy,,,,,,,. Here we show …

Photo-actuators via epitaxial growth of microcrystal arrays in polymer membranes

W Xu, DM Sanchez, U Raucci, H Zhou, X Dong, M Hu… - Nature Materials, 2023 - nature.com
Photomechanical crystals composed of three-dimensionally ordered and densely packed
photochromes hold promise for high-performance photochemical actuators. However, bulk …

Light-induced shape-memory polymers

A Lendlein, H Jiang, O Jünger, R Langer - Nature, 2005 - nature.com
Materials are said to show a shape-memory effect if they can be deformed and fixed into a
temporary shape, and recover their original, permanent shape only on exposure to an …

Photoinduced motions in azo-containing polymers

A Natansohn, P Rochon - Chemical reviews, 2002 - ACS Publications
Azobenzene photochemistry is a fascinating area of investigation, on one hand, because it
is fairly wellknown, 1 and on the other hand because it has produced and continues to …

Synthetic molecular motors and mechanical machines

ER Kay, DA Leigh, F Zerbetto - … Chemie International Edition, 2007 - Wiley Online Library
The widespread use of controlled molecular‐level motion in key natural processes suggests
that great rewards could come from bridging the gap between the present generation of …

Photochemistry of azobenzene-containing polymers

GS Kumar, DC Neckers - Chemical Reviews, 1989 - ACS Publications
Photochemical reactions which occur in smallmole-cules can also be induced to occur in
macromolecules. Though, in macromolecular environments there are constraints which are …