The chemistry and applications of flexible porous coordination polymers

N Behera, J Duan, W Jin, S Kitagawa - EnergyChem, 2021 - Elsevier
Since the late 1990s, much progress has been made in the field of the chemistry of flexible
porous coordination polymers (PCPs). Various PCP architectures have been recognized …

Theoretical and experimental advances in high-pressure behaviors of nanoparticles

L Meng, TV Vu, LJ Criscenti, TA Ho, Y Qin… - Chemical …, 2023 - ACS Publications
Using compressive mechanical forces, such as pressure, to induce crystallographic phase
transitions and mesostructural changes while modulating material properties in …

A Water‐Stable Cationic SIFSIX MOF for Luminescent Probing of Cr2O72− via Single‐Crystal to Single‐Crystal Transformation

R Sahoo, S Mondal, S Chand, AK Manna, MC Das - Small, 2023 - Wiley Online Library
The sensing and monitoring of toxic oxo‐anion contaminants in water are of significant
importance to biological and environmental systems. A rare hydro‐stable SIFSIX metal …

Structural Chemistry of Metal–Organic Frameworks under Hydrostatic Pressures

P Vervoorts, J Stebani, ASJ Mendez… - ACS Materials …, 2021 - ACS Publications
Studying the structural behavior of metal–organic frameworks (MOFs) under hydrostatic
pressures is a steadily growing area. The goal of active research is identification of …

Giant negative compressibility by liquid intrusion into superhydrophobic flexible nanoporous frameworks

M Tortora, P Zajdel, AR Lowe, M Chorążewski… - Nano …, 2021 - ACS Publications
Materials or systems demonstrating negative linear compressibility (NLC), whose size
increases (decreases) in at least one of their dimensions upon compression …

Negative Linear Compressibility in Organic–Inorganic Hybrid Perovskite [NH2NH3]X(HCOO)3 (X = Mn, Fe, Co)

PS Ghosh, I Ponomareva - The Journal of Physical Chemistry …, 2022 - ACS Publications
Hybrid organic–inorganic perovskites [NH2NH3][X (HCOO) 3](X= Mn, Fe, Co) have a so-
called “wine-rack” type of geometry that could give origin to the rare property of negative …

Engineering anomalous elastic properties of coordination polymers and their amorphization by employing flexible linkers

A Półrolniczak, S Sobczak, A Katrusiak - Journal of Materials Chemistry …, 2023 - pubs.rsc.org
The common property of all materials is their elasticity, directly related to the chemical
components and interactions in their structure. However, the progress in constructing better …

ZIF-75 under pressure: Negative linear compressibility and pressure-induced instability

F Colmenero, V Timón - Applied Sciences, 2022 - mdpi.com
Featured Application The zeolitic imidazolate framework ZIF-75 exhibits the negative linear
compressibility effect under small applied pressures with multiple potential applications …

Abnormal Compressive Behaviors of Metal–Organic Frameworks under Hydrostatic Pressure

Q Zeng, K Wang, B Zou - Langmuir, 2022 - ACS Publications
Intuition indicates that materials will contract in all crystal directions under hydrostatic
pressure, ie, all of their axes exhibit positive linear compressibility (PLC) when uniformly …

Nanoscale metal organic frameworks and their applications in disease diagnosis and therapy

C Hu, J Chen, H Zhang, L Wu, P Yang, X Hou - Microchemical Journal, 2022 - Elsevier
Nanoscale metal organic frameworks (nMOFs) are coordination polymers composed of
organic ligands and inorganic vertices at nanometer scale. Inherent biodegradability …