The chemistry and applications of flexible porous coordination polymers
Since the late 1990s, much progress has been made in the field of the chemistry of flexible
porous coordination polymers (PCPs). Various PCP architectures have been recognized …
porous coordination polymers (PCPs). Various PCP architectures have been recognized …
Theoretical and experimental advances in high-pressure behaviors of nanoparticles
Using compressive mechanical forces, such as pressure, to induce crystallographic phase
transitions and mesostructural changes while modulating material properties in …
transitions and mesostructural changes while modulating material properties in …
A Water‐Stable Cationic SIFSIX MOF for Luminescent Probing of Cr2O72− via Single‐Crystal to Single‐Crystal Transformation
The sensing and monitoring of toxic oxo‐anion contaminants in water are of significant
importance to biological and environmental systems. A rare hydro‐stable SIFSIX metal …
importance to biological and environmental systems. A rare hydro‐stable SIFSIX metal …
Structural Chemistry of Metal–Organic Frameworks under Hydrostatic Pressures
P Vervoorts, J Stebani, ASJ Mendez… - ACS Materials …, 2021 - ACS Publications
Studying the structural behavior of metal–organic frameworks (MOFs) under hydrostatic
pressures is a steadily growing area. The goal of active research is identification of …
pressures is a steadily growing area. The goal of active research is identification of …
Giant negative compressibility by liquid intrusion into superhydrophobic flexible nanoporous frameworks
Materials or systems demonstrating negative linear compressibility (NLC), whose size
increases (decreases) in at least one of their dimensions upon compression …
increases (decreases) in at least one of their dimensions upon compression …
Negative Linear Compressibility in Organic–Inorganic Hybrid Perovskite [NH2NH3]X(HCOO)3 (X = Mn, Fe, Co)
PS Ghosh, I Ponomareva - The Journal of Physical Chemistry …, 2022 - ACS Publications
Hybrid organic–inorganic perovskites [NH2NH3][X (HCOO) 3](X= Mn, Fe, Co) have a so-
called “wine-rack” type of geometry that could give origin to the rare property of negative …
called “wine-rack” type of geometry that could give origin to the rare property of negative …
Engineering anomalous elastic properties of coordination polymers and their amorphization by employing flexible linkers
The common property of all materials is their elasticity, directly related to the chemical
components and interactions in their structure. However, the progress in constructing better …
components and interactions in their structure. However, the progress in constructing better …
ZIF-75 under pressure: Negative linear compressibility and pressure-induced instability
F Colmenero, V Timón - Applied Sciences, 2022 - mdpi.com
Featured Application The zeolitic imidazolate framework ZIF-75 exhibits the negative linear
compressibility effect under small applied pressures with multiple potential applications …
compressibility effect under small applied pressures with multiple potential applications …
Abnormal Compressive Behaviors of Metal–Organic Frameworks under Hydrostatic Pressure
Q Zeng, K Wang, B Zou - Langmuir, 2022 - ACS Publications
Intuition indicates that materials will contract in all crystal directions under hydrostatic
pressure, ie, all of their axes exhibit positive linear compressibility (PLC) when uniformly …
pressure, ie, all of their axes exhibit positive linear compressibility (PLC) when uniformly …
Nanoscale metal organic frameworks and their applications in disease diagnosis and therapy
C Hu, J Chen, H Zhang, L Wu, P Yang, X Hou - Microchemical Journal, 2022 - Elsevier
Nanoscale metal organic frameworks (nMOFs) are coordination polymers composed of
organic ligands and inorganic vertices at nanometer scale. Inherent biodegradability …
organic ligands and inorganic vertices at nanometer scale. Inherent biodegradability …