Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Heteroleptic diimine–diphosphine Cu (I) complexes as an alternative towards noble-metal based photosensitizers: Design strategies, photophysical properties and …

Y Zhang, M Schulz, M Wächtler, M Karnahl… - Coordination Chemistry …, 2018 - Elsevier
Photoactive Cu (I) complexes are considered as a promising alternative to traditional noble-
metal complexes that are mainly based on Ru (II) and Ir (III). Therefore, in recent years …

Design of efficient thermally activated delayed fluorescence materials for pure blue organic light emitting diodes

Q Zhang, J Li, K Shizu, S Huang, S Hirata… - Journal of the …, 2012 - ACS Publications
Efficient thermally activated delayed fluorescence (TADF) has been characterized for a
carbazole/sulfone derivative in both solutions and doped films. A pure blue organic light …

Harvesting luminescence via harnessing the photophysical properties of transition metal complexes

PT Chou, Y Chi, MW Chung, CC Lin - Coordination Chemistry Reviews, 2011 - Elsevier
The main goal of this review is to provide systematic elucidation of the correlation between
structural characters and the photophysical properties of a series of heavy transition metal …

Thermally Activated Delayed Fluorescence (TADF) and Enhancing Photoluminescence Quantum Yields of [CuI(diimine)(diphosphine)]+ ComplexesPhotophysical …

CL Linfoot, MJ Leitl, P Richardson, AF Rausch… - Inorganic …, 2014 - ACS Publications
The complexes [Cu (I)(POP)(dmbpy)][BF4](1) and [Cu (I)(POP)(tmbpy)][BF4](2)(dmbpy= 4,
4′-dimethyl-2, 2′-bipyridyl; tmbpy= 4, 4′, 6, 6′-tetramethyl-2, 2′-bipyridyl; POP= bis [2 …

Luminescent complexes beyond the platinum group: the d10 avenue

A Barbieri, G Accorsi, N Armaroli - Chemical Communications, 2008 - pubs.rsc.org
Luminescent metal complexes are key materials for several applications such as lighting,
analytical probes, and lasers. In many cases compounds based on precious (ie platinum …

Systematic Investigation of the Metal-Structure–Photophysics Relationship of Emissive d10-Complexes of Group 11 Elements: The Prospect of Application in Organic …

CW Hsu, CC Lin, MW Chung, Y Chi… - Journal of the …, 2011 - ACS Publications
A series of new emissive group 11 transition metal d10-complexes 1–8 bearing
functionalized 2-pyridyl pyrrolide together with phosphine ancillary such as bis [2 …

Improving the photophysical properties of copper (I) bis (phenanthroline) complexes

A Lavie-Cambot, M Cantuel, Y Leydet… - Coordination Chemistry …, 2008 - Elsevier
Homoleptic copper (I) bis (2, 9-dialkyl-1, 10-phenanthroline) units, as well as a range of
related heteroleptic species, represent popular choices for building blocks in the …

Direct observation of intersystem crossing in a thermally activated delayed fluorescence copper complex in the solid state

L Bergmann, GJ Hedley, T Baumann, S Bräse… - Science …, 2016 - science.org
Intersystem crossing in thermally activated delayed fluorescence (TADF) materials is an
important process that controls the rate at which singlet states convert to triplets; however …

Design of a long-lifetime, earth-abundant, aqueous compatible Cu (I) photosensitizer using cooperative steric effects

CE McCusker, FN Castellano - Inorganic Chemistry, 2013 - ACS Publications
A new homoleptic Cu (I) photosensitizer,[Cu (dsbtmp) 2]+(dsbtmp= 2, 9-di (sec-butyl)-3, 4, 7,
8-tetramethyl-1, 10-phenanthroline), designed to exhibit cooperative steric hindrance …