Biological nitrogen fixation by the nitrogenase enzymes has long been a touchstone for
dinitrogen chemists. 1, 2 Both the enzymatic reduction and protonation of N2 mediated by …

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Nitrogenase enzymes are used by microorganisms for converting atmospheric N2 to
ammonia, which provides an essential source of N atoms for higher organisms. The active …

One of the most challenging problems in small molecule activation is the development of a
homogeneous catalyst for converting dinitrogen into ammonia at ambient temperatures and …

Understanding the coordination of dinitrogen to iron is important for understanding
biological nitrogen fixation as well as for designing synthetic systems that are capable of …

Publisher Summary The chemistry of metal–alkynyl compounds is developing at a rapid
pace. The bonds of alkynyl ligands, like those of organic alkynes have been shown to …

A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen
complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This …

We report a survey of the reactivity of the first isolable iron-hydride complexes with a
coordination number less than 5. The high-spin iron (II) complexes [(β-diketiminate) Fe (μ …

The first dinitrogen complex,[Ru (NH3) 5 (N2)] 2+, was identified in 1965 by Allen and
Senoff, 1 who were at-tempting to obtain [Ru (NH3) 6] 2+ using a method of preparation …

Despite renewed interest in carbon dioxide (CO2) reduction chemistry, examples of
homogeneous iron catalysts that hydrogenate CO2 are limited compared to their noble …