Ion mobility mass spectrometry (IM-MS) for structural biology: insights gained by measuring mass, charge, and collision cross section

E Christofi, P Barran - Chemical Reviews, 2023 - ACS Publications
The investigation of macromolecular biomolecules with ion mobility mass spectrometry (IM-
MS) techniques has provided substantial insights into the field of structural biology over the …

Instrumentation at the leading edge of proteomics

TM Peters-Clarke, JJ Coon, NM Riley - Analytical Chemistry, 2024 - ACS Publications
The proteome, or collection of proteoforms expressed in a biological system, is dynamic and
heterogeneous. As our appreciation for the complexity of the proteome has evolved, so have …

To 200,000 m/z and Beyond: Native Electron Capture Charge Reduction Mass Spectrometry Deconvolves Heterogeneous Signals in Large Biopharmaceutical …

KIP Le Huray, TP Wörner, T Moreira… - ACS Central …, 2024 - ACS Publications
Great progress has been made in the detection of large biomolecular analytes by native
mass spectrometry; however, characterizing highly heterogeneous samples remains …

Top-down protein analysis by tandem-trapped ion mobility spectrometry/mass spectrometry (tandem-TIMS/MS) coupled with ultraviolet photodissociation (UVPD) and …

FC Liu, ME Ridgeway, CA Wootton… - Journal of the …, 2023 - ACS Publications
“Top-down” proteomics analyzes intact proteins and identifies proteoforms by their intact
mass as well as the observed fragmentation pattern in tandem mass spectrometry (MS/MS) …

Mobility-Assisted Pseudo-MS3 Sequencing of Protein Ions

KA Graham, VJ Grisolia, NB Borotto - Journal of the American …, 2024 - ACS Publications
The sequencing of intact proteins within a mass spectrometer has many benefits but is
frequently limited by the fact that tandem mass spectrometry (MS/MS) techniques often …

Combining SDS‐PAGE to capillary zone electrophoresis‐tandem mass spectrometry for high‐resolution top‐down proteomics analysis of intact histone proteoforms

F Fang, G Gao, Q Wang, Q Wang, L Sun - Proteomics, 2024 - Wiley Online Library
Mass spectrometry (MS)‐based top‐down proteomics (TDP) analysis of histone proteoforms
provides critical information about combinatorial post‐translational modifications (PTMs) …

Top/Middle-Down Characterization of α-Synuclein Glycoforms

SA Miller, K Jeanne Dit Fouque, ER Hard… - Analytical …, 2023 - ACS Publications
α-Synuclein is an intrinsically disordered protein that plays a critical role in the pathogenesis
of neurodegenerative disorders, such as Parkinson's disease. Proteomics studies of human …

Top-down proteomics

DS Roberts, JA Loo, YO Tsybin, X Liu, S Wu… - Nature Reviews …, 2024 - nature.com
Proteoforms, which arise from post-translational modifications, genetic polymorphisms and
RNA splice variants, play a pivotal role as drivers in biology. Understanding proteoforms is …

Capillary zone electrophoresis‐high field asymmetric ion mobility spectrometry‐tandem mass spectrometry for top‐down characterization of histone proteoforms

Q Wang, F Fang, Q Wang, L Sun - Proteomics, 2024 - Wiley Online Library
Abstract Characterization of histone proteoforms with various post‐translational
modifications (PTMs) is critical for a better understanding of functions of histone proteoforms …

Conformational Characterization of Peptides and Proteins by 193 nm Ultraviolet Photodissociation in the Collision Cell of a Trapped Ion Mobility Spectrometry-Time-of …

JP Butalewicz, EE Escobar, CA Wootton… - Analytical …, 2024 - ACS Publications
Ultraviolet photodissociation (UVPD) has been shown to be a versatile ion activation
strategy for the characterization of peptides and intact proteins among other classes of …