Corner‐and Side‐Opened Cage Silsesquioxanes: Structural Effects on the Materials Properties

H Imoto, Y Ueda, Y Sato, M Nakamura… - European Journal of …, 2020 - Wiley Online Library
Open‐cage silsesquioxane, in which traditional closed‐cage silsesquioxane is partially
hydrolyzed, is a promising class of building blocks for constructing organic‐inorganic …

Polymers and cyclic compounds based on a side‐opening type cage silsesquioxane

H Imoto, Y Sato, K Naka - Journal of Polymer Science Part A …, 2019 - Wiley Online Library
Polymers having polyhedral oligomeric silsesquioxane (POSS) in the main chains are an
important class of organic–inorganic hybrid materials. Despite the increasing attention to the …

Palladium-Catalyzed Arylation of Open-Cage Silsesquioxanes toward Thermally Stable and Highly Dispersible Nanofillers

S Wada, H Imoto, K Naka - Bulletin of the Chemical Society of …, 2019 - academic.oup.com
Incompletely condensed polyhedral oligomeric silsesquioxanes (IC-POSS) are promising
building blocks for the development of organic-inorganic hybrid materials. Pd-catalyzed …

Soluble network polymers based on trifunctional open-cage silsesquioxanes

H Imoto, A Ishida, M Hashimoto, Y Mizoue… - Chemistry …, 2019 - academic.oup.com
Open-cage silsesquioxanes (IC-POSS, incompletely condensed polyhedral oligomeric
silsesquioxane) were herein employed for construction of network polymers by utilizing the …

Transition‐Metal‐Catalyzed Direct Arylation of Caged Silsesquioxanes: Substrate Scope and Mechanistic Study

H Imoto, S Wada, T Yumura… - European Journal of …, 2019 - Wiley Online Library
Caged silsesquioxane (polyhedral oligomeric silsesquioxane: POSS) is an important class
of organic‐inorganic hybrid molecules. The electronic properties of POSS have gradually …