Photoacoustic measurements of porphyrin triplet‐state quantum yields and singlet‐oxygen efficiencies

M Pineiro, AL Carvalho, MM Pereira… - … A European Journal, 1998 - Wiley Online Library
Photoacoustic calorimetry and luminescence techniques were used to measure singlet
oxygen quantum yields (ΦΔ) of selected 5, 10, 15, 20‐tetrakis (aryl) porphyrins and of the …

Mechanisms of singlet‐oxygen and superoxide‐ion generation by porphyrins and bacteriochlorins and their implications in photodynamic therapy

EFF Silva, C Serpa, JM Dąbrowski… - … A European Journal, 2010 - Wiley Online Library
New halogenated and sulfonated bacteriochlorins and their analogous porphyrins are
employed as photosensitizers of singlet oxygen and the superoxide ion. The mechanisms of …

[图书][B] Chemical kinetics: from molecular structure to chemical reactivity

L Arnaut, H Burrows - 2006 - books.google.com
Chemical Kinetics bridges the gap between beginner and specialist with a path that leads
the reader from the phenomenological approach to the rates of chemical reactions to the …

Heavy-atom effects on metalloporphyrins and polyhalogenated porphyrins

EG Azenha, AC Serra, M Pineiro, MM Pereira… - Chemical physics, 2002 - Elsevier
The photophysics of halogenated and metallated tetrakisphenylporphyrins is investigated
using single-photon counting, photoacoustic calorimetry and luminescence techniques. The …

Highly fluorescent open-shell NIR dyes: The time-dependence of back electron transfer in triarylamine-perchlorotriphenylmethyl radicals

A Heckmann, S Dümmler, J Pauli… - The Journal of …, 2009 - ACS Publications
Triarylamine-perchlorotriphenylmethyl radicals (TARA-PCTM) may be viewed as open-shell
mixed valence donor− acceptor compounds that exhibit strong charge-transfer (CT) bands in …

Design of porphyrin-based photosensitizers for photodynamic therapy

LG Arnaut - Advances in Inorganic Chemistry, 2011 - Elsevier
Porphyrin and metalloporphyrin derivatives are at the forefront of the photosensitizers
currently investigated for the photodynamic therapy (PDT) of cancer. Earlier examples …

Electron transfer from aromatic amines to excited coumarin dyes: fluorescence quenching and picosecond transient absorption studies

S Nad, H Pal - The Journal of Physical Chemistry A, 2000 - ACS Publications
Electron transfer (ET) from aniline, N-alkylanilines, N, N-dialkylanilines, and o-
phenylenediamine to a number of excited (S1) 4-CF3-coumarin dyes having differently …

An overview of continuum models for nonequilibrium solvation: Popular theories and new challenge

XY Li - International Journal of Quantum Chemistry, 2015 - Wiley Online Library
The effect of solvent on the electron transfer (ET) and spectral shifts has been the focus of
experimental and theoretical studies and a key quantity in these studies is the solvent …

Estimation of electronic coupling for intermolecular electron transfer from cross-reaction data

SF Nelsen, MN Weaver, Y Luo… - The journal of …, 2006 - ACS Publications
Sixty-five electron-transfer reactions including 27 new 0,+ 1 couples have been added to our
data set of cross-reactions between 0 and+ 1 couples, bringing it to 206 reactions involving …

Isolation of the latent precursor complex in electron-transfer dynamics. Intermolecular association and self-exchange with acceptor anion radicals

V Ganesan, SV Rosokha, JK Kochi - Journal of the American …, 2003 - ACS Publications
Transient [1: 1] complexes formed in the bimolecular interactions of electron acceptors (A)
with their reduced anion radicals (A-•) are detected and characterized in solution for the first …