Recognition and sensing of chiral organic molecules by chiral porphyrinoids: a review

G Travagliante, M Gaeta, R Purrello, A D'Urso - Chemosensors, 2021 - mdpi.com
Porphyrinoids are extremely attractive for their electronic, optical, and coordination
properties as well as for their versatile substitution at meso/β-positions. All these features …

Triazolated calix [4] semitubes: assembling strategies towards long multicalixarene architectures

M Malakhova, A Gorbunov, N Ozerov… - Organic Chemistry …, 2022 - pubs.rsc.org
Cone and 1, 3-alternate calix [4] arenes bearing pairs of 2-azidoethyl or propargyl groups,
and 1, 3-alternate calix [4] arenes having four 2-azidoethyl and four propargyl groups or …

Shrinkable/stretchable bis (calix [4] arenes) comprising photoreactive azobenzene or stilbene linkers

I Lentin, A Gorbunov, S Bezzubov, V Nosova… - Organic Chemistry …, 2023 - pubs.rsc.org
Semi-tubular bis (calixarenes) of photo-variable length were shown to be readily available
by linking together two calix [4] arene macrorings by means of two bifunctional azobenzene …

Assembling triazolated calix [4] semitubes by means of copper (I)-catalyzed azide–alkyne cycloaddition

A Gorbunov, N Ozerov, M Malakhova… - Organic Chemistry …, 2021 - pubs.rsc.org
Nine pairs of cone and 1, 3-alternate calix [4] arenes having distal propargyl or 2-azidoethyl
groups at their phenolic oxygen atoms were thoroughly studied during macrocyclization …

Effect of the buffer composition on the aggregation state of the zinc (II) tetra-spermine porphyrin derivative

G Travagliante, M Gaeta, CMA Gangemi… - Journal of Porphyrins …, 2023 - World Scientific
The aggregative state of the Zn (II) tetra-spermine porphyrin derivative, ZnTCPPSpm4, has
been investigated in the presence of different buffers at the same pH value: 5K (cacodylate) …

Self‐Assembled Chiral Film Based on Melanin Polymers

M Gaeta, G Travagliante, M Barcellona, ME Fragalà… - Chirality, 2024 - Wiley Online Library
Chirality plays a fundamental role in natural phenomena, yet its manifestation on solid
surfaces remains relatively unexplored. In this study, we investigate the formation of …

Building Triazolated Macrocycles from Bis-Propargylated Calix [4] arenes and Bis-Azidomethylated Azobenzene or Stilbene

I Lentin, I Korniltsev, A Gorbunov, D Cheshkov… - Molbank, 2023 - mdpi.com
Copper (I)-catalyzed azide-alkyne cycloaddition was employed to construct biscalixarene
assemblies from the calix [4] arene dipropargyl ethers and 4, 4′-bis-azidomethylated …

[PDF][PDF] Synthetic strategies for the functionalization of upper or lower rim of supramolecular calix [4] arene platform

B Uttam, S Polepalli, CP Rao - Arkivoc, 2022 - arkat-usa.org
In the broad area of supramolecular chemistry, the calix [n] arene provides a congenial
platform for synthetic modifications, and further has been a highly studied system and …

Chirogenesis in Molecular Aggregates

M Gaeta, A D'Urso, R Purrello - CHIROGENESIS IN CHEMICAL …, 2023 - World Scientific
Self-assembly process appears as a powerful and attractive strategy for constructing
complex supramolecules by spontaneous organization of appropriate building blocks …

Influence of H-bond competitors on the solvent-dependent structures of an octaurea-calix [4] tube

M Milone, I Pisagatti, G Gattuso, A Notti, MF Parisi… - RSC …, 2024 - pubs.rsc.org
A novel octaurea-calix [4] tube (UC4T) has been synthesized in three steps from the original
Beer's p-tert-butylcalix [4] tube ionophore. In a polar solvent (DMSO-d6), UC4T rapidly …