Organic synthesis using nitroxides

D Leifert, A Studer - Chemical Reviews, 2023 - ACS Publications
Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Powering up the future: radical polymers for battery applications

T Janoschka, MD Hager, US Schubert - Advanced Materials, 2012 - Wiley Online Library
Our society's dependency on portable electric energy, ie, rechargeable batteries, which
permit power consumption at any place and in any time, will eventually culminate in …

Chemical routes for the transformation of biomass into chemicals

A Corma, S Iborra, A Velty - Chemical reviews, 2007 - ACS Publications
Vegetable biomass is generated from CO2 and H2O using sunlight as the energy source,
producing O2 as a subproduct. The primary products formed are C6-and C5-sugars that …

Nitroxides: applications in synthesis and in polymer chemistry

L Tebben, A Studer - Angewandte Chemie International Edition, 2011 - Wiley Online Library
This Review describes the application of nitroxides to synthesis and polymer chemistry. The
synthesis and physical properties of nitroxides are discussed first. The largest section …

Organic polymer supports for synthesis and for reagent and catalyst immobilization

J Lu, PH Toy - Chemical reviews, 2009 - ACS Publications
Merrifield first reported the concept of solid-phase peptide synthesis using heterogeneous
chloromethylated polystyrene that was lightly cross-linked by divinylbenzene (Merrifield …

TEMPO in chemical transformations: from homogeneous to heterogeneous

HA Beejapur, Q Zhang, K Hu, L Zhu, J Wang… - ACS Catalysis, 2019 - ACS Publications
The organic nitroxyl radical, TEMPO (2, 2, 6, 6-tetramethylpiperidine-N-oxyl), finds a variety
of industrial applications for chemical transformations. Because of economic and …

Nitroxide radical polymers–a versatile material class for high-tech applications

KA Hansen, JP Blinco - Polymer Chemistry, 2018 - pubs.rsc.org
Nitroxides are a versatile class of stable free radicals that have long established themselves
in a wide range of applications. Their incorporation into macromolecular architectures has …

Using soluble polymer supports to facilitate homogeneous catalysis

DE Bergbreiter, J Tian, C Hongfa - Chemical Reviews, 2009 - ACS Publications
The most important application of polymers in synthetic chemistry is the use of cross-linked
polymers in solid phase synthesis and in various sorts of “purifications”. This is emphasized …

Stable organic radical polymers: synthesis and applications

K Zhang, MJ Monteiro, Z Jia - Polymer Chemistry, 2016 - pubs.rsc.org
There has been a resurgence in the development of new synthetic methods to produce
stable organic radical polymers (ORPs) with control over chemical composition and …

Photocrosslinked nitroxide polymer cathode-active materials for application in an organic-based paper battery

T Suga, H Konishi, H Nishide - Chemical Communications, 2007 - pubs.rsc.org
Photocrosslinked nitroxide polymer cathode-active materials for application in an organic-based
paper battery - Chemical Communications (RSC Publishing) DOI:10.1039/B618710B Royal …