Hydroamination, an atom-economic one-step reaction that refers to the addition of an NH
unit into CC/CX multiple bonds, provides an ideally efficient methodology to construct C–N …

This review summarizes the most noteworthy achievements in the field of C–O and C–N
bond formation by hydroalkoxylation and hydroamination reactions on unactivated alkenes …

Aminium radical cations have been extensively studied as electrophilic aminating species
that readily participate in C–N bond forming processes with alkenes and arenes. However …

We report here a photocatalytic method for the intermolecular anti-Markovnikov
hydroamination of unactivated olefins with primary alkyl amines to selectively furnish …

Secondary and tertiary alkylamines are privileged substance classes that are often found in
pharmaceuticals and other biologically active small molecules. Herein, we report their direct …

Hydroamination of alkenes catalyzed by transition-metal complexes is an atom-economical
method for the synthesis of amines, but reactions of unactivated alkenes remain inefficient …

An array of rare-earth bis (aminobenzyl) complexes supported by imidazolin-2-iminato
ligands were synthesized and structurally characterized. These complexes showed high …

Enantioenriched pyrrolidines and derivatives are ubiquitous substructures in compounds of
importance to medicinal and biological chemistry. Herein, we report an efficient cobalt …

The intermolecular anti‐Markovnikov hydroamination of vinylsilanes was achieved utilizing
five silyl‐substituted ortho‐terphenoxide yttrium complexes. The highest activity was …

The development of methods for the assembly of secondary α-alkyl amines remains a
central challenge to chemical synthesis because of their critical importance in modulating …