Controlling catalyst activity, chemoselectivity and stereoselectivity with the mechanical bond

AW Heard, JM Suárez, SM Goldup - Nature Reviews Chemistry, 2022 - nature.com
Mechanically interlocked molecules, such as rotaxanes and catenanes, are receiving
increased attention as scaffolds for the development of new catalysts, driven by both their …

The rise and promise of molecular nanotopology

QH Guo, Y Jiao, Y Feng, JF Stoddart - CCS Chemistry, 2021 - chinesechemsoc.org
Molecular nanotopology—a term we coined recently—is a rapidly developing field of
research that is emerging out of the confluence of chemical topology with the mechanical …

Distinctive features and challenges in catenane chemistry

HY Au-Yeung, Y Deng - Chemical Science, 2022 - pubs.rsc.org
From being an aesthetic molecular object to a building block for the construction of
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …

Mechanical interlocking enhances the electrocatalytic oxygen reduction activity and selectivity of molecular copper complexes

X Mo, Y Deng, SKM Lai, X Gao, HL Yu… - Journal of the …, 2023 - ACS Publications
Efficient O2 reduction reaction (ORR) for selective H2O generation enables advanced fuel
cell technology. Nonprecious metal catalysts are viable and attractive alternatives to state-of …

Stimuli‐Responsive Catenane‐Based Catalysts

A Bessaguet, Q Blancart‐Remaury… - Angewandte Chemie …, 2023 - Wiley Online Library
Rotaxanes and molecular knots exhibit particular properties resulting from the presence of a
mechanical bond within their structure that maintains the molecular components interlocked …

Broadband and strong visible-light-absorbing cuprous sensitizers for boosting photosynthesis

KK Chen, CC Qin, MJ Ding, S Guo… - Proceedings of the …, 2022 - National Acad Sciences
Rational construction of broadband and strong visible-light-absorbing (BSVLA) earth-
abundant complexes is of great importance for efficient and sustainable solar energy …

Macrocycle dynamics in a branched [8] catenane controlled by three different stimuli in three different regions

AWH Ng, SKM Lai, CC Yee… - Angewandte Chemie …, 2022 - Wiley Online Library
A branched [8] catenane from an efficient one‐pot synthesis (72% HPLC yield, 59% isolated
yield) featuring the simultaneous use of three kinds of templates and cucurbit [6] uril …

A Robust Pyrazolate Metal–Organic Framework for Efficient Catalysis of Dehydrogenative C–O Cross Coupling Reaction

RR Liang, Z Han, P Cai, Y Yang… - Journal of the …, 2024 - ACS Publications
Construction of robust heterogeneous catalysts with atomic precision is a long-sought
pursuit in the catalysis field due to its fundamental significance in taming chemical …

Fine-tuning of the optical output in a dual responsive catenane switch

Y Deng, SKM Lai, L Kong, HY Au-Yeung - Chemical Communications, 2021 - pubs.rsc.org
Fine-tuning of the optical output in a dual responsive catenane switch - Chemical
Communications (RSC Publishing) DOI:10.1039/D1CC00310K Royal Society of Chemistry …

Advancements and strategic approaches in catenane synthesis

Q Chen, K Zhu - Chemical Society Reviews, 2024 - pubs.rsc.org
Catenanes, a distinctive category of mechanically interlocked molecules composed of
intertwined macrocycles, have undergone significant advancements since their initial stages …