Controlling catalyst activity, chemoselectivity and stereoselectivity with the mechanical bond
Mechanically interlocked molecules, such as rotaxanes and catenanes, are receiving
increased attention as scaffolds for the development of new catalysts, driven by both their …
increased attention as scaffolds for the development of new catalysts, driven by both their …
The rise and promise of molecular nanotopology
Molecular nanotopology—a term we coined recently—is a rapidly developing field of
research that is emerging out of the confluence of chemical topology with the mechanical …
research that is emerging out of the confluence of chemical topology with the mechanical …
Distinctive features and challenges in catenane chemistry
HY Au-Yeung, Y Deng - Chemical Science, 2022 - pubs.rsc.org
From being an aesthetic molecular object to a building block for the construction of
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …
Mechanical interlocking enhances the electrocatalytic oxygen reduction activity and selectivity of molecular copper complexes
Efficient O2 reduction reaction (ORR) for selective H2O generation enables advanced fuel
cell technology. Nonprecious metal catalysts are viable and attractive alternatives to state-of …
cell technology. Nonprecious metal catalysts are viable and attractive alternatives to state-of …
Stimuli‐Responsive Catenane‐Based Catalysts
A Bessaguet, Q Blancart‐Remaury… - Angewandte Chemie …, 2023 - Wiley Online Library
Rotaxanes and molecular knots exhibit particular properties resulting from the presence of a
mechanical bond within their structure that maintains the molecular components interlocked …
mechanical bond within their structure that maintains the molecular components interlocked …
Broadband and strong visible-light-absorbing cuprous sensitizers for boosting photosynthesis
KK Chen, CC Qin, MJ Ding, S Guo… - Proceedings of the …, 2022 - National Acad Sciences
Rational construction of broadband and strong visible-light-absorbing (BSVLA) earth-
abundant complexes is of great importance for efficient and sustainable solar energy …
abundant complexes is of great importance for efficient and sustainable solar energy …
Macrocycle dynamics in a branched [8] catenane controlled by three different stimuli in three different regions
A branched [8] catenane from an efficient one‐pot synthesis (72% HPLC yield, 59% isolated
yield) featuring the simultaneous use of three kinds of templates and cucurbit [6] uril …
yield) featuring the simultaneous use of three kinds of templates and cucurbit [6] uril …
A Robust Pyrazolate Metal–Organic Framework for Efficient Catalysis of Dehydrogenative C–O Cross Coupling Reaction
Construction of robust heterogeneous catalysts with atomic precision is a long-sought
pursuit in the catalysis field due to its fundamental significance in taming chemical …
pursuit in the catalysis field due to its fundamental significance in taming chemical …
Fine-tuning of the optical output in a dual responsive catenane switch
Y Deng, SKM Lai, L Kong, HY Au-Yeung - Chemical Communications, 2021 - pubs.rsc.org
Fine-tuning of the optical output in a dual responsive catenane switch - Chemical
Communications (RSC Publishing) DOI:10.1039/D1CC00310K Royal Society of Chemistry …
Communications (RSC Publishing) DOI:10.1039/D1CC00310K Royal Society of Chemistry …
Advancements and strategic approaches in catenane synthesis
Q Chen, K Zhu - Chemical Society Reviews, 2024 - pubs.rsc.org
Catenanes, a distinctive category of mechanically interlocked molecules composed of
intertwined macrocycles, have undergone significant advancements since their initial stages …
intertwined macrocycles, have undergone significant advancements since their initial stages …