Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

D Troegel, J Stohrer - Coordination Chemistry Reviews, 2011 - Elsevier
Hydrosilylation of olefins is the key catalytic reaction for the production of industrially
important organosilicon compounds such as organofunctional silanes and silicones …

Traffic lights for catalysis: Stimuli‐responsive molecular and extended catalytic systems

GC Thaggard, J Haimerl, RA Fischer… - Angewandte Chemie …, 2023 - Wiley Online Library
The advances made in the field of stimuli‐responsive catalysis during the last five years with
a focus on the novel recently‐emerged directions and applications have been surveyed …

PDMS curing inhibition on 3D-printed molds: why? Also, how to avoid it?

B Venzac, S Deng, Z Mahmoud, A Lenferink… - Analytical …, 2021 - ACS Publications
Three-dimensional (3D)-printing techniques such as stereolithography (SLA) are currently
gaining momentum for the production of miniaturized analytical devices and molds for soft …

[HTML][HTML] Platinum-catalyzed hydrosilylation in polymer chemistry

RY Lukin, AM Kuchkaev, AV Sukhov… - Polymers, 2020 - mdpi.com
This paper addresses a review of platinum-based hydrosilylation catalysts. The main field of
application of these catalysts is the curing of silicone polymers. Since the 1960s, this area …

Catalytic systems for the cross‐linking of organosilicon polymers

D Wang, J Klein, E Mejía - Chemistry–An Asian Journal, 2017 - Wiley Online Library
Silicones and silicone rubbers are omnipresent in household and industrial products such
as lubricants, coatings, sealants, insulators, medical devices, etc. This plethora of …

Cyclometalated platinum (II) complexes simultaneously catalyze the cross-linking of polysiloxanes and function as luminophores

MV Dobrynin, EV Sokolova, MA Kinzhalov… - ACS Applied Polymer …, 2021 - ACS Publications
A family of the C, N-cyclometalated species [Pt (ppy) Cl (PPh3)],[Pt (ppy) Cl (CNCy)],[Pt
(ppy)(CNCy)(PPh3)](OTf), and [Pt (ppy)(CNCy) 2](BF4)(ppy= 2-phenylpyridinato-C 2, N; Cy …

Silacyclopropylideneplatinum (0) complex as a robust and efficient hydrosilylation catalyst

T Troadec, A Prades, R Rodriguez, R Mirgalet… - Inorganic …, 2016 - ACS Publications
The base-stabilized silacyclopropylidene 1 behaves as a versatile strongly nucleophilic
ligand toward transition metals. The strong silylene–metal binding related to both increased …

Catalyst design of Vaska-type iridium complexes for highly efficient synthesis of π-conjugated enamines

A Tahara, Y Miyamoto, R Aoto, K Shigeta, Y Une… - …, 2015 - ACS Publications
The appropriate design of a ligand (L) in IrCl (CO)(L) 2 (4) realized the efficient synthesis of
π-conjugated enamines possessing hole-transport properties. The iridium complex with …

Rhodium (I)-catalysed cross-linking of polysiloxanes conducted at room temperature

MV Dobrynin, C Pretorius, DV Kama, A Roodt… - Journal of …, 2019 - Elsevier
Abstract Acetylacetonate and 4-arylimino-2-pentanonate carbonyl complexes of rhodium
(I)[Rh (RC (O) C (R') C (O) R “)(CO) 2](1: R= Me, R'= H, R''= Me; 2: R= Me, R'= Cl, R''= Me; 3 …

Iridium-PPh3 Catalysts for Conversion of Amides to Enamines

Y Une, A Tahara, Y Miyamoto, Y Sunada… - …, 2019 - ACS Publications
Studies on the deactivation mechanism of the reaction of N, N-dialkylamides with TMDS
catalyzed by Vaska's complex, IrCl (CO)(PPh3) 2 (1a), triggered the discovery of highly …