Hydrogen energy: Development prospects and materials

SP Filippov, AB Yaroslavtsev - Russian Chemical Reviews, 2021 - iopscience.iop.org
The review addresses the prospects of global hydrogen energy development. Particular
attention is given to the design of materials for sustainable hydrogen energy applications …

Catalytic (de) hydrogenation promoted by non-precious metals–Co, Fe and Mn: recent advances in an emerging field

GA Filonenko, R Van Putten, EJM Hensen… - Chemical Society …, 2018 - pubs.rsc.org
Catalytic hydrogenation and dehydrogenation reactions form the core of the modern
chemical industry. This vast class of reactions is found in any part of chemical synthesis …

[HTML][HTML] Reversible ammonia-based and liquid organic hydrogen carriers for high-density hydrogen storage: Recent progress

JW Makepeace, T He, C Weidenthaler… - international journal of …, 2019 - Elsevier
Liquid hydrogen carriers are considered to be attractive hydrogen storage options because
of their ease of integration into existing chemical transportation infrastructures when …

Metal–ligand bifunctional catalysis: the “accepted” mechanism, the issue of concertedness, and the function of the ligand in catalytic cycles involving hydrogen atoms

PA Dub, JC Gordon - ACS Catalysis, 2017 - ACS Publications
For years, following the ideas of Shvo and Noyori, the core assumption of metal–ligand
bifunctional molecular catalysis has relied on the direct involvement of the chelating ligand …

Cooperative approaches in catalytic hydrogenation and dehydrogenation

MA Stevens, AL Colebatch - Chemical Society Reviews, 2022 - pubs.rsc.org
Metal–ligand cooperativity (MLC) is an established strategy for developing effective
hydrogenation and dehydrogenation catalysts. Metal–metal cooperativity (MMC) in …

Metal‐Free Dehydrogenation of N‐Heterocycles by Ternary h‐BCN Nanosheets with Visible Light

M Zheng, J Shi, T Yuan, X Wang - Angewandte Chemie, 2018 - Wiley Online Library
An efficient metal‐free catalytic system has been developed based on hexagonal boron
carbon nitride (h‐BCN) nanosheets for the dehydrogenation of N‐heterocycles with visible …

Modern technologies of hydrogen production

I Stenina, A Yaroslavtsev - Processes, 2022 - mdpi.com
Transitioning to energy-saving and renewable energy sources is impossible without
accelerated development of hydrogen energy and hydrogen technologies. This review …

Catalytic Formic Acid Dehydrogenation and CO2 Hydrogenation Using Iron PNRP Pincer Complexes with Isonitrile Ligands

JB Curley, NE Smith, WH Bernskoetter, N Hazari… - …, 2018 - ACS Publications
It has previously been demonstrated that complexes of the form (iPrPNP) Fe (H)(C≡
NR)(iPrPNP= N (CH2CH2P (iPr) 2) 2–, R= 2, 6-dimethylphenyl or 4-methoxyphenyl), which …

Mechanistic insight into the azo radical-promoted dehydrogenation of heteroarene towards N-heterocycles

AK Bains, D Adhikari - Catalysis Science & Technology, 2020 - pubs.rsc.org
Borrowing hydrogenation-promoted annulations are considered to be important reactions to
synthesize wide variety of N-heterocycles. In these processes, the dehydrogenation of …

The role of proton shuttles in the reversible activation of hydrogen via metal–ligand cooperation

NE Smith, WH Bernskoetter… - Journal of the American …, 2019 - ACS Publications
The reversible activation of H2 via a pathway involving metal–ligand cooperation (MLC) is
proposed to be important in many transition metal catalyzed hydrogenation and …