Programmable heating and quenching for efficient thermochemical synthesis
Conventional thermochemical syntheses by continuous heating under near-equilibrium
conditions face critical challenges in improving the synthesis rate, selectivity, catalyst …
conditions face critical challenges in improving the synthesis rate, selectivity, catalyst …
Nonequilibrium thermodynamics in biochemical systems and its application
D Zhang, Q Ouyang - Entropy, 2021 - mdpi.com
Living systems are open systems, where the laws of nonequilibrium thermodynamics play
the important role. Therefore, studying living systems from a nonequilibrium thermodynamic …
the important role. Therefore, studying living systems from a nonequilibrium thermodynamic …
Conservatively Perturbed Equilibrium (CPE) in chemical kinetics
Abstract The phenomenon of “Conservatively Perturbed Equilibrium”(CPE) in chemical
kinetics is distinguished using a sequence of first-order reactions (linear mechanism) and …
kinetics is distinguished using a sequence of first-order reactions (linear mechanism) and …
Reciprocal relations between kinetic curves
We study coupled irreversible processes. For linear or linearized kinetics with
microreversibility,, the kinetic operator K is symmetric in the entropic inner product. This form …
microreversibility,, the kinetic operator K is symmetric in the entropic inner product. This form …
Decoding complexity of chemical reactions
GS Yablonsky - Theoretical Foundations of Chemical Engineering, 2014 - Springer
Decoding Complexity of Chemical Reactions1 Page 1 ISSN 0040 5795, Theoretical
Foundations of Chemical Engineering, 2014, Vol. 48, No. 5, pp. 608–613. © Pleiades …
Foundations of Chemical Engineering, 2014, Vol. 48, No. 5, pp. 608–613. © Pleiades …
Thermodynamic time invariances for dual kinetic experiments: Nonlinear single reactions and more
For dual kinetic experiments, ie, experiments performed in batch or steady-state plug flow
reactors from reciprocal initial conditions, thermodynamic (space-) time invariances for all …
reactors from reciprocal initial conditions, thermodynamic (space-) time invariances for all …
New patterns in steady-state chemical kinetics: intersections, coincidences, map of events (two-step mechanism)
New patterns of steady-state chemical kinetics for continuously stirred-tank reactors (CSTR)
have been found, ie, intersections, maxima and coincidences, for two-step mechanism A↔ …
have been found, ie, intersections, maxima and coincidences, for two-step mechanism A↔ …
Experimental confirmation of a new invariant for a non-linear chemical reaction
The first non-Onsager thermodynamic invariant for a non-linear chemical system was found
experimentally in all domains using “the dual kinetic experiment” in a batch reactor in which …
experimentally in all domains using “the dual kinetic experiment” in a batch reactor in which …
Joint kinetics: A new paradigm for chemical kinetics and chemical engineering
Joint kinetics, a new paradigm for chemical kinetics and chemical engineering, is proposed.
Its main idea is performing a battery of kinetic experiments from special initial compositions …
Its main idea is performing a battery of kinetic experiments from special initial compositions …
New invariances for chemical reactions from Scaled Incremental Conversion (SIC)
For the two-step chemical reaction A⇄ B⇄ C, invariant dependences of a new type have
been found. These invariants relate concentration dependences which are started from the …
been found. These invariants relate concentration dependences which are started from the …