Rise of conjugated poly-ynes and poly (metalla-ynes): from design through synthesis to structure–property relationships and applications
Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …
with potential application in various domains of science. The key factors responsible for the …
Metal alkynyl σ complexes: Synthesis and materials
NJ Long, CK Williams - Angewandte Chemie International …, 2003 - Wiley Online Library
Metal alkynyl complexes hold a fascination for synthetic chemists, structural chemists, and
materials scientists alike. Harnessing the unique overlap of metal and carbon orbitals is a …
materials scientists alike. Harnessing the unique overlap of metal and carbon orbitals is a …
Organometallic Complexes for Nonlinear Optics. 30.1 Electrochromic Linear and Nonlinear Optical Properties of Alkynylbis(diphosphine)ruthenium Complexes
CE Powell, MP Cifuentes, JP Morrall… - Journal of the …, 2003 - ACS Publications
A combination of cyclic voltammetry, UV− vis− NIR spectroelectrochemistry, time-dependent
density functional theory (TD-DFT), and Z-scan measurements employing a modified …
density functional theory (TD-DFT), and Z-scan measurements employing a modified …
Allenylidene and higher cumulenylidene complexes
V Cadierno, J Gimeno - Chemical reviews, 2009 - ACS Publications
Although the free allenylidene species: CdCdCH2 was originally identified in 1961 (trapped
in cold matrixes), 1 it is 1976 when the isolation of the first allenylidene complexes [M …
in cold matrixes), 1 it is 1976 when the isolation of the first allenylidene complexes [M …
Simultaneous bridge-localized and mixed-valence character in diruthenium radical cations featuring diethynylaromatic bridging ligands
MA Fox, B Le Guennic, RL Roberts… - Journal of the …, 2011 - ACS Publications
A series of bimetallic ruthenium complexes [{Ru (dppe) Cp*} 2 (μ-C CArC C)] featuring
diethynylaromatic bridging ligands (Ar= 1, 4-phenylene, 1, 4-naphthylene, 9, 10-anthrylene) …
diethynylaromatic bridging ligands (Ar= 1, 4-phenylene, 1, 4-naphthylene, 9, 10-anthrylene) …
Charge transfer and delocalization in conjugated (ferrocenylethynyl) oligothiophene complexes
Y Zhu, MO Wolf - Journal of the American Chemical Society, 2000 - ACS Publications
A series of conjugated mono (ferrocenylethynyl) oligothiophene and bis (ferrocenylethynyl)
oligothiophene complexes have been prepared. The cyclic voltammograms of the …
oligothiophene complexes have been prepared. The cyclic voltammograms of the …
Quantum Interference in Mixed‐Valence Complexes: Tuning Electronic Coupling Through Substituent Effects
Abstract Whilst 2‐or 5‐OMe groups on the bridging phenylene ring in [{Cp*(dppe) RuC≡ C}
2 (μ‐1, 3‐C6H4)]+ have little influence on the electronic structure of this weakly coupled …
2 (μ‐1, 3‐C6H4)]+ have little influence on the electronic structure of this weakly coupled …
Divinylphenylene-Bridged Diruthenium Complexes Bearing Ru(CO)Cl(PiPr3)2 Entities
J Maurer, B Sarkar, B Schwederski, W Kaim… - …, 2006 - ACS Publications
The divinylphenylene-bridged diruthenium complexes (E, E)-[{(P i Pr3) 2 (CO) ClRu} 2 (μ-
HC CHC6H4CH CH-1, 3)](m-2) and (E, E)-[{(P i Pr3) 2 (CO) ClRu} 2 (μ-HC CHC6H4CH CH …
HC CHC6H4CH CH-1, 3)](m-2) and (E, E)-[{(P i Pr3) 2 (CO) ClRu} 2 (μ-HC CHC6H4CH CH …
Organometallic Single-Molecule Electronics: Tuning Electron Transport through X(diphosphine)2FeC4Fe(diphosphine)2X Building Blocks by Varying the Fe–X–Au …
A series of X (depe) 2FeC C–C CFe (depe) 2X complexes (depe= 1, 2-bis
(diethylphosphino) ethane; X= I 1, NCMe 2, N2 3, C2H 4, C2SnMe3 5, C4SnMe3 6, NCSe 7 …
(diethylphosphino) ethane; X= I 1, NCMe 2, N2 3, C2H 4, C2SnMe3 5, C4SnMe3 6, NCSe 7 …
Electron-rich piano-stool iron σ-acetylides bearing a functional aryl group. synthesis and characterization of iron (II) and iron (III) complexes
R Denis, L Toupet, F Paul, C Lapinte - Organometallics, 2000 - ACS Publications
The synthesis and characterization of a family of para-functionalized complexes 3a− k,[(η2-
dppe)(η5-C5Me5) Fe (C⋮ CC6H4X)](dppe= 1, 2-(diphenylphosphino) ethane; X= NO2, CN …
dppe)(η5-C5Me5) Fe (C⋮ CC6H4X)](dppe= 1, 2-(diphenylphosphino) ethane; X= NO2, CN …