Front velocity dependence on vinyl ether and initiator concentration in radical‐induced cationic frontal polymerization of epoxies

BR Groce, DP Gary, JK Cantrell… - Journal of Polymer …, 2021 - Wiley Online Library
Formulations containing vinyl ethers and epoxy were successfully polymerized through a
radical‐induced cationic frontal polymerization mechanism, using an iodonium salt …

An epoxy adhesive crosslinked through radical‐induced cationic frontal polymerization

M Turani, A Baggio, V Casalegno… - Macromolecular …, 2021 - Wiley Online Library
UV‐initiated cationic frontal polymerization is exploited as a solvent‐free, extremely fast, and
low‐temperature technique to obtain epoxy‐based adhesives. Epoxy formulations are …

Mathematical modeling of frontal polymerization

JA Pojman - Mathematical Modelling of Natural Phenomena, 2019 - mmnp-journal.org
Frontal polymerization is way to convert liquid resin into a solid material with a self-
propagating reaction. The reaction spreads like a flame from the heat of the reaction that …

Photoinduced cationic frontal polymerization of epoxy–carbon fibre composites

M Sangermano, I Antonazzo, L Sisca… - Polymer …, 2019 - Wiley Online Library
UV‐activated frontal polymerization was exploited for the preparation of epoxy–carbon fibre
composites. The curing process was investigated showing the frontal behaviour, and the …

Frontal polymerization of deep eutectic solvents composed of acrylic and methacrylic acids

KF Fazende, M Phachansitthi… - Journal of Polymer …, 2017 - Wiley Online Library
Frontal polymerization of deep eutectic solvents (DESs) made with acrylic or methacrylic
acid as the monomer and hydrogen bond donor was studied. Fronts with acrylic acid and …

The effect of acrylate functionality on frontal polymerization velocity and temperature

S Bynum, M Tullier, C Morejon‐Garcia… - Journal of Polymer …, 2019 - Wiley Online Library
Frontal polymerization is a method of converting monomer (s) to polymer via a localized
reaction zone that propagates from the coupling of thermal diffusion with the Arrhenius …

Synthesis and characterization of thiol‐acrylate hydrogels using a base‐catalyzed Michael addition for 3D cell culture applications

AH Khan, JK Cook, WJ Wortmann III… - … Research Part B …, 2020 - Wiley Online Library
There is significant interest in developing new approaches for culturing mammalian cells in
a three‐dimensional (3D) environment due to the fact that it better recapitulates the in vivo …

Frontally polymerized foams: thermodynamic and kinetical aspects of front hindrance by particles

P Lepcio, J Daguerre-Bradford, AM Cristadoro… - Materials …, 2023 - pubs.rsc.org
Frontal polymerization (FP) is a solvent-free, energy-efficient process where a self-
propagating polymerization reaction with a characteristic sharp temperature gradient at the …

[图书][B] Synthesis of Thiol-Acrylate Hydrogels for 3D Cell Culture and Microfluidic Applications

AH Khan - 2022 - search.proquest.com
Globally cell culture is an $18.98 billion industry as of 2020, with an 11.6 percent annual
growth rate. Drug discovery has an estimated worth of $69.8 billion in 2020 and is predicted …

Methods and compositions for thiol-acrylate based matertals for 3D cell culturing in a microfluidic device

A Melvin, J Pojman, A Khan - US Patent 11,767,516, 2023 - Google Patents
Provided are thiol-acrylate hydrogels and tunable cell culture materials including thiol-
acrylate hydrogels, and methods of making thereof. Also provided are systems for forming …