[PDF][PDF] Advances in thermodiffusion and thermophoresis (Soret effect) in liquid mixtures
M Eslamian - Frontiers in Heat and Mass Transfer (FHMT), 2012 - researchgate.net
Recent advances in thermodiffusion (Soret effect) in binary and higher multicomponent
liquid mixtures are reviewed. The mixtures studied include the hydrocarbon, associating …
liquid mixtures are reviewed. The mixtures studied include the hydrocarbon, associating …
Internal degrees of freedom as a basis for isotopic effects in thermodiffusion
SN Semenov, ME Schimpf - The Journal of Physical Chemistry B, 2021 - ACS Publications
We present a model that relates isotope effects in thermodiffusion to changes in internal
degrees of freedom associated with rotational and vibrational motion. The model uses …
degrees of freedom associated with rotational and vibrational motion. The model uses …
Nonequilibrium thermodynamic material transport equations for thermodiffusion of isotopes and isomers in multicomponent systems
SN Semenov, ME Schimpf - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
We extend our nonequilibrium thermodynamic model of thermodiffusion in binary systems to
multi-component mixtures. The fundamental parameter is the difference in molecular entropy …
multi-component mixtures. The fundamental parameter is the difference in molecular entropy …
Statistical Mechanic and Phenomenological Approaches to Isomeric Effects in Thermodiffusion
SN Semenov, ME Schimpf - The Journal of Physical Chemistry B, 2022 - ACS Publications
We present a model that explains variance in the thermodiffusion of hydrocarbon isomers in
binary liquid mixtures. The model relies on material transport equations for binary …
binary liquid mixtures. The model relies on material transport equations for binary …
Statistical thermodynamics of material transport in non-isothermal binary systems
SN Semenov - Europhysics Letters, 2012 - iopscience.iop.org
The material transport equations derived by non-equilibrium thermodynamics are used to
describe the material transport in binary non-isothermal molecular systems. The chemical …
describe the material transport in binary non-isothermal molecular systems. The chemical …
Thermoosomosis in microfluidic devices containing a temperature gradient normal to the channel walls
SN Semenov, ME Schimpf - The European Physical Journal E, 2019 - Springer
We analyze a microfluidic pump from the literature that utilizes a flat channel with boundary
walls at different temperatures and tilted elongated pillars within in order to construct an …
walls at different temperatures and tilted elongated pillars within in order to construct an …
[HTML][HTML] Comparative Examination of Nonequilibrium Thermodynamic Models of Thermodiffusion in Liquids
SN Semenov, ME Schimpf - Proceedings, 2019 - mdpi.com
We analyze existing models for material transport in non-isothermal non-electrolyte liquid
mixtures that utilize non-equilibrium thermodynamics. Many different sets of equations for …
mixtures that utilize non-equilibrium thermodynamics. Many different sets of equations for …
Statistical Thermodynamics of Material Transport in Non-Isothermal Mixtures
This chapter outlines a theoretical framework for the microscopic approach to material
transport in liquid mixtures, and applies that framework to binary one-phase systems. The …
transport in liquid mixtures, and applies that framework to binary one-phase systems. The …
[PDF][PDF] Thermodynamic Theory of Isotope Effects in Thermodiffusion of Silicate Melts
Isotope effects in the thermodiffusion of dilute atomic liquids are examined using a non-
equilibrium thermodynamic model, where the thermodynamic parameters are calculated …
equilibrium thermodynamic model, where the thermodynamic parameters are calculated …