While the blocking barrier (Ueff) and blocking temperature (TB) for “Dysprocenium” SIMs
have been increased beyond liquid N2 temperature, device fabrication of these molecules …

Due to their fascinating structures and heterometallic synergistic effects in catalysis,
heterometallic clusters with metal–metal (M–M) bonds have attracted the interest of chemists …

Incorporation of secondary metal ions into heterobimetallic complexes has emerged as an
attractive strategy for rational tuning of compounds' properties and reactivity, but direct …

A selective extraction system of thorium (IV), formed with a TSIL derived from ciprofloxacin
and [BMIM][NTf2] as a co-solvent, is described. Under acidic conditions, this IL solution was …

Fragmentation methods applied to multireference wave functions constitute a road toward
the application of highly accurate ab initio wave function calculations to large molecules and …

Compared with the prevalent metal–metal bond in transition metals, examples of the
actinide–metal bond in heterometallic clusters are rare. Herein, a series of heterometallic …

Metal-metal bonds in complexes with d-block transition metals are common; but those with
metal–metal bonds involving both p-, d-, and f-block metals are extremely rare. Here, we …

Treatment of [UIV (N3)(TrenTIPS)](1, TrenTIPS={N (CH2CH2NSiPri3) 3} 3−) with excess Li
resulted in the isolation of [{UIV (μ-NLi2)(TrenTIPS)} 2](2), which exhibits a diuranium …

Recent advances enabled the discovery of heterometallic molecules for many metals: main
group, d-block, lanthanides, and some actinides (U, Th). These complexes have at least two …

Three-center two-electron bridging bonding plays a vital role in rationalizing structures and
stabilities of certain molecules. Herein, the π electron rule of pyrene (C16H10) was …