Aromatic rings in chemical and biological recognition: energetics and structures

LM Salonen, M Ellermann… - Angewandte Chemie …, 2011 - Wiley Online Library
This review describes a multidimensional treatment of molecular recognition phenomena
involving aromatic rings in chemical and biological systems. It summarizes new results …

Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials

G Aromí, LA Barrios, O Roubeau, P Gamez - Coordination Chemistry …, 2011 - Elsevier
The current great interest in preparing functional metal-organic materials is inevitably
associated with tremendous research efforts dedicated to the design and synthesis of new …

Aromatische Ringe in chemischer und biologischer Erkennung: Energien und Strukturen

LM Salonen, M Ellermann, F Diederich - Angewandte Chemie, 2011 - Wiley Online Library
Abstract Dieser Aufsatz beschreibt Phänomene der molekularen Erkennung von
aromatischen Ringen in chemischen und biologischen Systemen in einem …

A simple approach for predicting the spin state of homoleptic Fe (II) tris-diimine complexes

H Phan, JJ Hrudka, D Igimbayeva… - Journal of the …, 2017 - ACS Publications
We propose a simple method for predicting the spin state of homoleptic complexes of the Fe
(II) d6 ion with chelating diimine ligands. The approach is based on the analysis of a single …

Spin crossover in iron (II) complexes of 3, 4, 5-tri-substituted-1, 2, 4-triazole (Rdpt), 3, 5-di-substituted-1, 2, 4-triazolate (dpt−), and related ligands

HLC Feltham, AS Barltrop, S Brooker - Coordination Chemistry Reviews, 2017 - Elsevier
A general introduction to spin crossover involving iron (II) is provided. Then the 26 examples
of 3, 4, 5-tri-substituted-1, 2, 4-triazole (mostly Rdpt and Rppt) ligands and the 11 examples …

Solid Versus Solution Spin Crossover and the Importance of the Fe–N C (X) Angle

S Rodriguez-Jimenez, S Brooker - Inorganic chemistry, 2017 - ACS Publications
A new family of mononuclear [FeII (Rdpt) 2 (NCE) 2] complexes (E= S, Se, or BH3) is formed
by 1: 2 reaction of [FeII (pyridine) 4 (NCE) 2] with the monotopic pyridyl triazole ligand 4-(4 …

Extension of azine-triazole synthesis to azole-triazoles reduces ligand field, leading to spin crossover in tris-L Fe (II)

S Singh, S Brooker - Inorganic Chemistry, 2020 - ACS Publications
The first examples of azole-triazole R at ligands, bidentate L 4NMeIm (3-(1-methyl-1 H-
imidazol-4-yl)-5-phenyl-4-(p-tolyl)-4 H-1, 2, 4-triazole) and L 4SIm (4-(5-phenyl-4-(p-tolyl)-4 …

Solvent Polarity Predictably Tunes Spin Crossover T1/2 in Isomeric Iron(II) Pyrimidine Triazoles

S Rodriguez-Jimenez, AS Barltrop, NG White… - Inorganic …, 2018 - ACS Publications
Two isomeric pyrimidine-based Rdpt-type triazole ligands were made: 4-(4-methylphenyl)-3-
(2-pyrimidyl)-5-phenyl-4 H-1, 2, 4-triazole (L 2pyrimidine) and 4-(4-methylphenyl)-3-(4 …

Nano-magnetic materials: spin crossover compounds vs. single molecule magnets vs. single chain magnets

S Brooker, JA Kitchen - Dalton Transactions, 2009 - pubs.rsc.org
Brief introductions to spin crossover (SCO), single molecule magnetism (SMM) and single
chain magnetism (SCM) are provided. Each section is illustrated by selected examples that …

Fine-tuning of the spin-crossover properties of Fe (III) complexes via ligand design

D Vidal, J Cirera, J Ribas-Arino - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Exploring the chemical space of a given ligand aiming to modulate its ligand field strength is
a versatile strategy for the fine-tuning of physical properties such as the transition …