Bright side of lignin depolymerization: toward new platform chemicals

Z Sun, B Fridrich, A De Santi, S Elangovan… - Chemical …, 2018 - ACS Publications
Lignin, a major component of lignocellulose, is the largest source of aromatic building blocks
on the planet and harbors great potential to serve as starting material for the production of …

Carboxylate-assisted transition-metal-catalyzed C− H bond functionalizations: mechanism and scope

L Ackermann - Chemical reviews, 2011 - ACS Publications
The site-selective formation of carbonrcarbon bonds through direct functionalizations of
otherwise unreactive carbonrhydrogen bonds constitutes an economically attractive strategy …

Direct α-alkylation of acetophenones with benzhydrols as well as 1-phenylethanols using Amberlyst-15/ionic liquid as an efficient catalytic system

KV Wagh, BM Bhanage - ACS Sustainable Chemistry & …, 2016 - ACS Publications
The direct α-alkylation of acetophenones with benzhydrols as well as 1-phenylethanols
using Amberlyst-15/[Bmim][PF6] ionic liquid as an affordable catalytic system has been …

Arylglyoxals in synthesis of heterocyclic compounds

B Eftekhari-Sis, M Zirak, A Akbari - Chemical reviews, 2013 - ACS Publications
Heterocycles are an extraordinarily important class of compounds, making up more than half
of all known organic compounds. Heterocycles are present in a wide variety of drugs, most …

meta-Selective C–H bond alkylation with secondary alkyl halides

N Hofmann, L Ackermann - Journal of the American Chemical …, 2013 - ACS Publications
Ruthenium catalysts enabled C–H bond functionalizations on arenes with challenging
secondary alkyl halides. Particularly, ruthenium (II) biscarboxylate complexes proved to be …

Cobalt-catalyzed C–H arylations, benzylations, and alkylations with organic electrophiles and beyond

L Ackermann - The Journal of Organic Chemistry, 2014 - ACS Publications
Catalytic C–H functionalizations are increasingly viable tools for sustainable syntheses. In
recent years, inexpensive cobalt complexes were identified as powerful catalysts for C–H …

Activation of “Inert” Alkenyl/Aryl C O Bond and Its Application in Cross‐Coupling Reactions

BJ Li, DG Yu, CL Sun, ZJ Shi - Chemistry–A European Journal, 2011 - Wiley Online Library
Enol and phenol functionalities are very common in organic molecules. Utilization of these
materials is very appealing in organic synthesis because they are important alternatives to …

Nickel-catalyzed C–H/C–O coupling of azoles with phenol derivatives

K Muto, J Yamaguchi, K Itami - Journal of the American Chemical …, 2012 - ACS Publications
The first nickel-catalyzed C–H bond arylation of azoles with phenol derivatives is described.
The new Ni (cod) 2/dcype catalytic system is active for the coupling of various phenol …

Metal-catalyzed direct alkylations of (hetero) arenes via C–H bond cleavages with unactivated alkyl halides

L Ackermann - Chemical communications, 2010 - pubs.rsc.org
Significant progress has been made in direct alkylations of (hetero) arenes with unactivated
alkyl halides. Thus, C–H bond functionalizations were accomplished with β-hydrogen …

Regioselectivity in palladium-catalysed direct arylation of 5-membered ring heteroaromatics

CB Bheeter, L Chen, JF Soulé, H Doucet - Catalysis Science & …, 2016 - pubs.rsc.org
In recent years, palladium-catalysed arylation of heteroaromatics via C–H bond activation
has become a popular method for generating carbon–carbon bonds. For this reaction, a …