Bright side of lignin depolymerization: toward new platform chemicals
Lignin, a major component of lignocellulose, is the largest source of aromatic building blocks
on the planet and harbors great potential to serve as starting material for the production of …
on the planet and harbors great potential to serve as starting material for the production of …
Carboxylate-assisted transition-metal-catalyzed C− H bond functionalizations: mechanism and scope
L Ackermann - Chemical reviews, 2011 - ACS Publications
The site-selective formation of carbonrcarbon bonds through direct functionalizations of
otherwise unreactive carbonrhydrogen bonds constitutes an economically attractive strategy …
otherwise unreactive carbonrhydrogen bonds constitutes an economically attractive strategy …
Direct α-alkylation of acetophenones with benzhydrols as well as 1-phenylethanols using Amberlyst-15/ionic liquid as an efficient catalytic system
KV Wagh, BM Bhanage - ACS Sustainable Chemistry & …, 2016 - ACS Publications
The direct α-alkylation of acetophenones with benzhydrols as well as 1-phenylethanols
using Amberlyst-15/[Bmim][PF6] ionic liquid as an affordable catalytic system has been …
using Amberlyst-15/[Bmim][PF6] ionic liquid as an affordable catalytic system has been …
Arylglyoxals in synthesis of heterocyclic compounds
Heterocycles are an extraordinarily important class of compounds, making up more than half
of all known organic compounds. Heterocycles are present in a wide variety of drugs, most …
of all known organic compounds. Heterocycles are present in a wide variety of drugs, most …
meta-Selective C–H bond alkylation with secondary alkyl halides
N Hofmann, L Ackermann - Journal of the American Chemical …, 2013 - ACS Publications
Ruthenium catalysts enabled C–H bond functionalizations on arenes with challenging
secondary alkyl halides. Particularly, ruthenium (II) biscarboxylate complexes proved to be …
secondary alkyl halides. Particularly, ruthenium (II) biscarboxylate complexes proved to be …
Cobalt-catalyzed C–H arylations, benzylations, and alkylations with organic electrophiles and beyond
L Ackermann - The Journal of Organic Chemistry, 2014 - ACS Publications
Catalytic C–H functionalizations are increasingly viable tools for sustainable syntheses. In
recent years, inexpensive cobalt complexes were identified as powerful catalysts for C–H …
recent years, inexpensive cobalt complexes were identified as powerful catalysts for C–H …
Activation of “Inert” Alkenyl/Aryl C O Bond and Its Application in Cross‐Coupling Reactions
BJ Li, DG Yu, CL Sun, ZJ Shi - Chemistry–A European Journal, 2011 - Wiley Online Library
Enol and phenol functionalities are very common in organic molecules. Utilization of these
materials is very appealing in organic synthesis because they are important alternatives to …
materials is very appealing in organic synthesis because they are important alternatives to …
Nickel-catalyzed C–H/C–O coupling of azoles with phenol derivatives
K Muto, J Yamaguchi, K Itami - Journal of the American Chemical …, 2012 - ACS Publications
The first nickel-catalyzed C–H bond arylation of azoles with phenol derivatives is described.
The new Ni (cod) 2/dcype catalytic system is active for the coupling of various phenol …
The new Ni (cod) 2/dcype catalytic system is active for the coupling of various phenol …
Metal-catalyzed direct alkylations of (hetero) arenes via C–H bond cleavages with unactivated alkyl halides
L Ackermann - Chemical communications, 2010 - pubs.rsc.org
Significant progress has been made in direct alkylations of (hetero) arenes with unactivated
alkyl halides. Thus, C–H bond functionalizations were accomplished with β-hydrogen …
alkyl halides. Thus, C–H bond functionalizations were accomplished with β-hydrogen …
Regioselectivity in palladium-catalysed direct arylation of 5-membered ring heteroaromatics
CB Bheeter, L Chen, JF Soulé, H Doucet - Catalysis Science & …, 2016 - pubs.rsc.org
In recent years, palladium-catalysed arylation of heteroaromatics via C–H bond activation
has become a popular method for generating carbon–carbon bonds. For this reaction, a …
has become a popular method for generating carbon–carbon bonds. For this reaction, a …