Site-selective C–H functionalization via synergistic use of electrochemistry and transition metal catalysis

KJ Jiao, YK Xing, QL Yang, H Qiu… - Accounts of chemical …, 2020 - ACS Publications
Conspectus Electrochemical synthesis of organic compounds has emerged as an attractive
and environmentally benign alternative to conventional approaches for oxidation and …

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Computational studies of synthetically relevant homogeneous organometallic catalysis involving Ni, Pd, Ir, and Rh: an overview of commonly employed DFT methods …

T Sperger, IA Sanhueza, I Kalvet… - Chemical …, 2015 - ACS Publications
The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

Ruthenium (II)-catalyzed C–H bond activation and functionalization

PB Arockiam, C Bruneau, PH Dixneuf - Chemical reviews, 2012 - ACS Publications
The catalytic functionalization of unreactive C− H bonds has recently brought a revolution in
synthetic methodologies for the production of pharmaceuticals and natural products and for …

Carboxylate-assisted ruthenium-catalyzed alkyne annulations by C–H/Het–H bond functionalizations

L Ackermann - Accounts of Chemical Research, 2014 - ACS Publications
To improve the atom-and step-economy of organic syntheses, researchers would like to
capitalize upon the chemistry of otherwise inert carbon–hydrogen (C–H) bonds. During the …

Weakly Coordinating Directing Groups for Ruthenium (II)‐Catalyzed C H Activation

S De Sarkar, W Liu, SI Kozhushkov… - … Synthesis & Catalysis, 2014 - Wiley Online Library
Synthetically useful functional groups, including ketones, amides, carbamates, carboxylic
acids, aldehydes or ethers, have been identified as weakly coordinating directing groups in …

Carboxylic acids as directing groups for C− H bond functionalization

M Pichette Drapeau, LJ Gooßen - Chemistry–A European …, 2016 - Wiley Online Library
The selective transformation of C− H bonds is one of the most desirable approaches to
creating complexity from simple building blocks. Several directing groups are efficient in …

[HTML][HTML] Transition metal-catalyzed organic reactions in undivided electrochemical cells

C Ma, P Fang, D Liu, KJ Jiao, PS Gao, H Qiu… - Chemical Science, 2021 - pubs.rsc.org
Transition metal-catalyzed organic electrochemistry is a rapidly growing research area
owing in part to the ability of metal catalysts to alter the selectivity of a given transformation …

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

SI Kozhushkov, L Ackermann - Chemical science, 2013 - pubs.rsc.org
Significant progress has been accomplished in direct olefinations through twofold C–H bond
functionalization of arenes and heteroarenes employing readily accessible, selective and …

meta-Selective C–H bond alkylation with secondary alkyl halides

N Hofmann, L Ackermann - Journal of the American Chemical …, 2013 - ACS Publications
Ruthenium catalysts enabled C–H bond functionalizations on arenes with challenging
secondary alkyl halides. Particularly, ruthenium (II) biscarboxylate complexes proved to be …