From short to medium range order in glasses and melts by diffraction and Raman spectroscopy

JWE Drewitt, L Hennet… - Reviews in Mineralogy …, 2022 - pubs.geoscienceworld.org
The structure of glasses and the melts from which they are formed is intrinsically disordered,
making their structural characterization difficult. Whilst the structure of solid minerals can be …

The short-range order (SRO) and structure

GS Henderson, JF Stebbins - Reviews in Mineralogy …, 2022 - pubs.geoscienceworld.org
Magmas are mixtures of melt, crystals and dissolved gasses with or without crystalline
material (Mysen and Richet 2019). They play an important role in igneous processes …

Computer simulation as a tool for the interpretation of total scattering data from glasses and liquids

AK Soper - Molecular Simulation, 2012 - Taylor & Francis
Ever since the pioneering work by McGreevy and Pusztai [Mol. Simul. 1 (1988), pp. 359–
367] in developing the reverse Monte Carlo (RMC) technique, computer simulation has …

The structure of molten calcium ferrite under various redox conditions

C Shi, OLG Alderman, A Tamalonis… - … of the Royal …, 2023 - royalsocietypublishing.org
Laser-heated melts based on the 43CaO–57Fe2O3− x eutectic, close to the calcium ferrite
(CF) composition, were measured with high-energy X-ray diffraction using aerodynamic …

Investigation of the discoloration of smalt pigment in historic paintings by micro-X-ray absorption spectroscopy at the Co K-edge

L Robinet, M Spring, S Pagès-Camagna… - Analytical …, 2011 - ACS Publications
Smalt was commonly used as a pigment by artists between the 16th and 18th centuries. It is
a powdered blue potash glass colored by cobalt ions and often degrades causing dramatic …

Effect of the alkali vs iron ratio on glass transition temperature and vibrational properties of synthetic basalt-like glasses

M Cassetta, B Giannetta, F Enrichi, C Zaccone… - … Acta Part A: Molecular …, 2023 - Elsevier
Volcanic eruptions generate huge amounts of material with a wide range of compositions
and therefore different physicochemical properties. We present a combined Raman and …

Effect of iron redox ratio on the structures of boroaluminosilicate glasses

MI Tuheen, W Sun, J Du - Journal of the American Ceramic …, 2022 - Wiley Online Library
Iron oxide is commonly found in natural or industrial glass compositions and can exist as
ferrous (Fe2+) or ferric (Fe3+) species, with their ratios depending on glass composition …

Iron K-edge X-ray absorption near-edge structure spectroscopy of aerodynamically levitated silicate melts and glasses

OLG Alderman, MC Wilding, A Tamalonis… - Chemical …, 2017 - Elsevier
The local structure about Fe (II) and Fe (III) in silicate melts was investigated in-situ using
iron K-edge X-ray absorption near-edge structure (XANES) spectroscopy. An aerodynamic …

Diluted Fe3+ in silicate glasses: Structural effects of Fe-redox state and matrix composition. An optical absorption and X-band/Q-band EPR study

V Vercamer, G Lelong, H Hijiya, Y Kondo… - Journal of Non …, 2015 - Elsevier
Sodium-alkaline earth-silicate glasses, of nominal molar composition 16Na 2 O–10RO–
74SiO 2 (R= Ca,(Ca, Mg) and Mg) doped with 0.5 wt.% of Fe 2 O 3, were studied by UV …

Iron-induced structural rearrangements and their impact on sulfur solubility in borosilicate-based nuclear waste glasses

X Xu, M Bertani, R Saini, S Kamali… - The Journal of …, 2024 - ACS Publications
The work presented in this review combines the strength of experimental and computational
materials science to understand the iron-induced structural rearrangements in peralkaline …