Emerging Trends in Cross-Coupling: Twelve-Electron-Based L1Pd(0) Catalysts, Their Mechanism of Action, and Selected Applications

SJ Firsan, V Sivakumar, TJ Colacot - Chemical Reviews, 2022 - ACS Publications
Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Selection of boron reagents for Suzuki–Miyaura coupling

AJJ Lennox, GC Lloyd-Jones - Chemical Society Reviews, 2014 - pubs.rsc.org
Suzuki–Miyaura (SM) cross-coupling is arguably the most widely-applied transition metal
catalysed carbon–carbon bond forming reaction to date. Its success originates from a …

Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond

X Liu, C Xu, M Wang, Q Liu - Chemical reviews, 2015 - ACS Publications
Method B 692 3.7. Selective Trifluoromethylation of Multi-Functional Substrates 693 3.8.
Enantioselective Trifluoromethylation 695 3.8. 1. Aldehydes and Ketones: With Cinchona …

Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link

AA Thomas, SE Denmark - Science, 2016 - science.org
Despite the widespread application of Suzuki-Miyaura cross-coupling to forge carbon-
carbon bonds, the structure of the reactive intermediates underlying the key transmetalation …

[图书][B] New trends in cross-coupling: theory and applications

TJ Colacot - 2014 - books.google.com
Palladium-catalysed cross-coupling reactions constitute a powerful class of chemical
methods for the creation of carbon-carbon and carbon-heteroatom bonds used in organic …

Stereospecific Pd-catalyzed cross-coupling reactions of secondary alkylboron nucleophiles and aryl chlorides

L Li, S Zhao, A Joshi-Pangu, M Diane… - Journal of the …, 2014 - ACS Publications
We report the development of a Pd-catalyzed process for the stereospecific cross-coupling
of unactivated secondary alkylboron nucleophiles and aryl chlorides. This process tolerates …

Organotrifluoroborates: Another branch of the mighty oak

GA Molander - The Journal of Organic Chemistry, 2015 - ACS Publications
Over the past two decades, organotrifluoroborates have evolved from being chemical
curiosities to important reagents for the elaboration of organic molecules. Aside from their …

Direct Light‐Enabled Access to α‐Boryl Radicals: Application in the Stereodivergent Synthesis of Allyl Boronic Esters

A Marotta, H Fang, CE Adams… - Angewandte Chemie …, 2023 - Wiley Online Library
Operationally simple strategies to assemble boron containing organic frameworks are highly
enabling in organic synthesis. While conventional retrosynthetic logic has engendered many …

Elucidating the role of the boronic esters in the Suzuki–Miyaura reaction: structural, kinetic, and computational investigations

AA Thomas, AF Zahrt, CP Delaney… - Journal of the American …, 2018 - ACS Publications
The Suzuki–Miyaura reaction is the most practiced palladium-catalyzed, cross-coupling
reaction because of its broad applicability, low toxicity of the metal (B), and the wide variety …

Empowering boronic acids as hydroxyl synthons for aryne induced three-component coupling reactions

R Fan, S Liu, Q Yan, Y Wei, J Wang, Y Lan, J Tan - Chemical Science, 2023 - pubs.rsc.org
Boronic acids have become one of the most prevalent classes of reagents in modern
organic synthesis, displaying various reactivity profiles via C–B bond cleavage. Herein, we …