Oxidative addition and reductive elimination at main-group element centers
T Chu, GI Nikonov - Chemical reviews, 2018 - ACS Publications
Oxidative addition and reductive elimination are key steps in a wide variety of catalytic
reactions mediated by transition-metal complexes. Historically, this reactivity has been …
reactions mediated by transition-metal complexes. Historically, this reactivity has been …
Where silylene–silicon centres matter in the activation of small molecules
Small molecules such as H2, N2, CO, NH3, O2 are ubiquitous stable species and their
activation and role in the formation of value-added products are of fundamental importance …
activation and role in the formation of value-added products are of fundamental importance …
A bis (silylene)-stabilized diphosphorus compound and its reactivity as a monophosphorus anion transfer reagent
In contrast to the well-established transition-metal-mediated activation of white phosphorus
(P4), the metal-free direct functionalization of P4 has remained rare. The conversion of P4 …
(P4), the metal-free direct functionalization of P4 has remained rare. The conversion of P4 …
The chemistry of yellow arsenic
M Seidl, G Balázs, M Scheer - Chemical reviews, 2019 - ACS Publications
The generation and handling of the light-sensitive and metastable yellow arsenic (As4) is
extremely challenging. In view of recent breakthroughs in synthesizing As4 storage …
extremely challenging. In view of recent breakthroughs in synthesizing As4 storage …
Recent progress in the chemistry of metal amidinates and guanidinates: syntheses, catalysis and materials
FT Edelmann - Advances in organometallic chemistry, 2013 - Elsevier
This review provides a comprehensive overview of the most recent progress in chemistry
and applications of metal complexes containing heteroallylic ligands such as amidinates …
and applications of metal complexes containing heteroallylic ligands such as amidinates …
Unexpected White Phosphorus (P4) Activation Modes with Silylene‐Substituted o‐Carboranes and Access to an Isolable 1,3‐Diphospha‐2,4‐disilabutadiene
New types of metal‐free white phosphorus (P4) activation are reported. While the phosphine‐
silylene‐substituted dicarborane 1, CB‐SiP (CB= ortho‐C, C′‐C2B10H10, Si= PhC (tBuN) …
silylene‐substituted dicarborane 1, CB‐SiP (CB= ortho‐C, C′‐C2B10H10, Si= PhC (tBuN) …
An Isolable 2,5‐Disila‐3,4‐Diphosphapyrrole and a Conjugated Si=P−Si=P−Si=N Chain Through Degradation of White Phosphorus with a N,N‐Bis(Silylenyl)Aniline
White phosphorus (P4) undergoes degradation to P2 moieties if exposed to the new N, N‐
bis (silylenyl) aniline PhNSi2 1 (Si= Si [N (tBu)] 2CPh), furnishing the first isolable 2, 5‐disila …
bis (silylenyl) aniline PhNSi2 1 (Si= Si [N (tBu)] 2CPh), furnishing the first isolable 2, 5‐disila …
Oxidation reactions of a versatile, two-coordinate, acyclic iminosiloxysilylene
D Reiter, P Frisch, D Wendel, FM Hörmann… - Dalton …, 2020 - pubs.rsc.org
Due to their outstanding reactivity, acyclic silylenes have emerged as attractive
organosilicon alternatives for transition metal complexes on the way to metal-free catalysis …
organosilicon alternatives for transition metal complexes on the way to metal-free catalysis …
From a phosphaketenyl‐functionalized germylene to 1, 3‐digerma‐2, 4‐diphosphacyclobutadiene
The first 4π‐electron resonance‐stabilized 1, 3‐digerma‐2, 4‐diphosphacyclobutadiene
[LH2Ge2P2] 4 (LH= CH [CHNDipp] 2 Dipp= 2, 6‐iPr2C6H3) with four‐coordinate …
[LH2Ge2P2] 4 (LH= CH [CHNDipp] 2 Dipp= 2, 6‐iPr2C6H3) with four‐coordinate …
[HTML][HTML] Activation of phosphorus by group 14 elements in low oxidation states
The activation of phosphorus remains a popular and competitive area of research driven by
the dual goals of finding ways to avoid the environmentally questionable P–Cl compounds …
the dual goals of finding ways to avoid the environmentally questionable P–Cl compounds …