[HTML][HTML] N-Acetonitrile functionalized 3-nitrotriazole: Precursor to nitrogen rich stable and insensitive energetic materials

P Bhatia, PS Priya, P Das, D Kumar - Energetic Materials Frontiers, 2024 - Elsevier
In the field of energetic materials, prime attention has been given to the synthesis of
environmentally compatible energetic materials having an adequate balance between …

Understanding the Stability of Highly Nitrated Sensitive Pyrazole Isomers

J Singh, V Thaltiri, RJ Staples, JM Shreeve - Organic Letters, 2024 - ACS Publications
Two energetic isomers of chemically unstable 3, 5-bis (dinitromethyl)-4-nitro-1 H-pyrazole
(2), namely, 4-methyl-3, 5-dinitro-1-(trinitromethyl)-1 H-pyrazole (4) and 5-methyl-3, 4-dinitro …

Intramolecular assembly of dinitromethyl and bistetrazole: a strategy for constructing advanced and environmentally friendly high-energy density materials

X Yu, J Tang, C Lei, C Xue, G Cheng, C Xiao… - Journal of Materials …, 2024 - pubs.rsc.org
Bistetrazoles have received extensive attention from researchers in the field of energetic
materials due to their high heat of formation (ΔHf= 4.06 kJ g− 1) and high nitrogen content …

1-Trinitromethyl-3, 5-dinitro-4-nitroaminopyrazole: Intramolecular Full Nitration and Strong Intermolecular H-Bonds toward Highly Dense Energetic Materials

N Ding, Q Sun, X Xu, W Zhang, C Zhao… - The Journal of …, 2024 - ACS Publications
Full nitration is one of the most effective strategies used in synthesizing high-density
energetic materials, but this strategy has reached its limit because the resultant compounds …

Construction of Adaptive Deformation Block: Rational Molecular Editing of the N-Rich Host Molecule to Remove Water from the Energetic Hydrogen-Bonded Organic …

Z Wang, Q Lai, P Yin, S Pang - ACS Applied Materials & Interfaces, 2024 - ACS Publications
Energetic hydrogen-bonded organic frameworks (E-HOFs), as a type of energetic material,
spark fresh vitality to the creation of high energy density materials (HEDMs). However, E …

Trinitromethyl-Substituted 1H-1,2,4-Triazole Bridging Nitropyrazole: A Strategy of Utterly Manipulable Nitration Achieving High-Energy Density Material

P Yi, C Lin, X Yi, P He, T Wang… - ACS Applied Materials & …, 2024 - ACS Publications
Nitro groups have been demonstrated to play a decisive role in the development of the most
powerful known energetic materials. Two trinitromethyl-substituted 1 H-1, 2, 4-triazole …

Assembling of Nitropyrazoles into Tetranitroacetimidic Acid (TNAA): A Pathway to High-Performance Energetic Oxidizers through Dual C/N-Functionalization

W Xie, X Jiang, M Sun, X Zhang, P Yin, Q Lai - Organic Letters, 2024 - ACS Publications
In this work, incorporating nitropyraozles into tetranitroacetimidic acid (TNAA) resulted in two
analogues of isomeric TNAA-like compounds (3 and 5). These compounds exhibit excellent …

Encapsulating Azolates Within Cationic Metal–Organic Frameworks for High‐Energy‐Density Materials

N Ding, C Zhao, J Zhang, Y Du, Q Sun, S Li… - Advanced …, 2024 - Wiley Online Library
Despite the synthesis of numerous cationic metal‐organic frameworks (CMOFs), their
counter anions have been primarily limited to inorganic Cl−, NO3−, ClO4−, BF4−, and …

Energetic Multifunctionalized Nitro/nitramino Isomeric Pyrazole-Tetrazole Hybrids: Enhancing Density and Detonation Properties through Hydrogen Bonding and π-π …

V Thaltiri, RJ Staples, MS Jean'ne - Journal of Materials Chemistry A, 2024 - pubs.rsc.org
This study focuses on synthesizing high-density isomeric pyrazole-tetrazoles and their
energetic salts, with a particular emphasis on improving detonation performance. First …

Bucking the trend: gathering 12 nitro groups towards an ultrahigh-energy oxidizer with superior stability

N Ding, X Xu, X Kang, Z Wei, Q Sun, S Li… - CCS …, 2024 - chinesechemsoc.org
Polynitro compounds play indispensable roles as high-energy oxidizers in solid propellants
and space exploration. Generally, the number of nitro groups governs the energy and …