Heterocyclic compounds are among the most prestigious and valuable chemical molecules
with diverse and magnificent applications in various sciences. Due to the remarkable and …

Microwave-assisted organic synthesis has been widely studied and deliberated, opening up
some controversial issues as well. Nowadays, microwave chemistry is a mature technology …

Allenes with two carbon–carbon double bonds belong to a unique class of unsaturated
hydrocarbons. The central carbon atom of allene is sp hybridized and forms two σ-bonds …

[4+ 2] oxidative Diels–Alder reaction of readily available alkynols with maleimide is achieved
for the rapid access of pthalimide-fused multicyclic compounds. The reaction is proposed to …

A general and versatile Ni-catalyzed propargylic substitution of propargyl acetates has been
developed using a broad range of phosphorus nucleophiles, including phosphine oxides …

Ene-allenes serve as versatile building blocks in organic synthesis, and the development of
their efficient preparation is valuable. Herein the synthesis of boryl-substituted ene-allenes …

A photoexcited palladium-catalyzed synthesis of chiral allenes from alkynes via a sequence
of isomerization and deracemization is disclosed. This method offers an efficient and cost …

For a long time, allenes—and cumulenic systems in general—played a relatively minor role
in Diels–Alder cycloadditions. This situation has changed, since allenes are more readily …

A variety of chiral nine‐membered N‐heterocycles were prepared in moderate to good
yields with high diastereoselectivity through a silver (I)‐catalyzed [3+ 2] cycloaddition and [3 …

We develop a copper-catalyzed disilylation of polysubstituted pent-1-en-4-yn-3-yl acetate
derivatives, which in one pot furnishes the bis (silyl)-substituted vinylallenes in moderate …