Porous organic polymers for drug delivery: Hierarchical pore structures, variable morphologies, and biological properties

Y Tang, A Varyambath, Y Ding, B Chen, X Huang… - Biomaterials …, 2022 - pubs.rsc.org
Porous organic polymers have received considerable attention in recent years because of
their applicability as biomaterials. In particular, their hierarchical pore structures, variable …

Enzyme-mimicking single atoms enable selectivity control in visible-light-driven oxidation/ammoxidation to afford bio-based nitriles

Y Meng, J Huang, J Li, Y Jian, S Yang, H Li - Green Chemistry, 2023 - pubs.rsc.org
Nitriles are versatile nitrogen-containing scaffolds that exist widely in medicines, dyes and
functional materials, and are typically synthesized over homogeneous catalysts under …

Mesoporous α-Al2O3-supported PdCu bimetallic nanoparticle catalyst for the selective semi-hydrogenation of alkynes

J Li, W Suo, Y Huang, M Chen, H Ma, C Liu… - Journal of Colloid and …, 2023 - Elsevier
The selective hydrogenation of alkynes to alkenes is widely applied in the chemical industry;
nevertheless, achieving highly selective hydrogenation with high catalytic activity is …

[HTML][HTML] Ring-closing C–O/C–O metathesis of ethers with primary aliphatic alcohols

H Liu, Q Huang, R Liao, M Li, Y Xie - Nature Communications, 2023 - nature.com
In canonical organic chemistry textbooks, the widely adopted mechanism for the classic
transetherifications between ethers and alcohols starts with the activation of the ether in …

[HTML][HTML] Aromatic halogenation using carborane catalyst

CN Kona, R Oku, S Nakamura, M Miura, K Hirano… - Chem, 2024 - cell.com
Haloarenes have been an important class of chemicals in the modern organic chemistry
field because the halide functionality offers numerous possible transformations. Classical …

Recent metal-catalyzed methods for thioether synthesis

VJ Geiger, RM Oechsner, PH Gehrtz, I Fleischer - Synthesis, 2022 - thieme-connect.com
This review summarizes the more recent methods (since 2015) for the synthesis of
thioethers using homogeneous metals as catalysts. The thioether moiety can be found in …

Synergy between ionic capacity and intrinsic porosity in imidazolium-based cationic organic polymers and its effect on anionic dye adsorption

SQ Fu, MZ Zhu, B Xue, PN Liu - Macromolecules, 2022 - ACS Publications
A series of novel imidazolium-based cationic organic polymers (COPs) with various ionic
capacities (ICs) and porosities were synthesized by adjusting the structure of the building …

Electron-poor phosphines enable the selective semihydrogenation reaction of alkynes with Pd on carbon catalysts

J Ballesteros-Soberanas… - The Journal of Physical …, 2023 - ACS Publications
An alternative to the Lindlar catalyst for the semihydrogenation reaction of alkynes to
alkenes is of high interest. Here we show that palladium on carbon (Pd/C), ie, a widely …

Direct thioether metathesis enabled by in situ formed Pd nanocluster catalysts

T Matsuyama, T Yatabe, T Yabe… - Catalysis Science & …, 2024 - pubs.rsc.org
Thioether metathesis has been noted as a complementary thioether synthesis methodology
with cross-coupling reactions, which can be applied to late-stage diversification. However …

An Efficient Direct Arylation Polycondensation via C− S Bond Cleavage

M Zhang, BB Zhang, Q Lin, Z Jiang… - Angewandte Chemie …, 2023 - Wiley Online Library
The direct arylation polycondensation (DArP) has become one of the most important
methods to construct conjugated polymers (CPs). However, the homocoupling side …