Carbene polymerization from the catalyzed decomposition of diazo compounds: Mechanism and modern development

F Li, L Xiao, B Li, X Hu, L Liu - Coordination Chemistry Reviews, 2022 - Elsevier
Carbene polymerization from the catalyzed decomposition of diazo compounds is a unique
non-petroleum-based C1 polymerization pathway toward high-density functional polyolefins …

[HTML][HTML] Cyclo-and polyphosphazenes for biomedical applications

G Casella, S Carlotto, F Lanero, M Mozzon… - Molecules, 2022 - mdpi.com
Cyclic and polyphosphazenes are extremely interesting and versatile substrates
characterized by the presence of-P= N-repeating units. The chlorine atoms on the P atoms in …

[HTML][HTML] Nickel(II)-catalyzed living polymerization of diazoacetates toward polycarbene homopolymer and polythiophene-block-polycarbene copolymers

L Zhou, L Xu, X Song, SM Kang, N Liu… - Nature Communications, 2022 - nature.com
Diazoacetate polymerization has attracted considerable research attention because it is an
effective approach for fabricating carbon–carbon (C–C) main chain polymers. However …

Terminal functionalization with a triptycene motif that dramatically changes the structural and physical properties of an amorphous polymer

F Ishiwari, G Okabe, H Ogiwara, T Kajitani… - Journal of the …, 2018 - ACS Publications
A surprising terminal-group effect on the structural and physical properties of an amorphous
polymer is reported. We recently demonstrated that triptycene derivatives with substituents at …

A dinuclear mechanism implicated in controlled carbene polymerization

AV Zhukhovitskiy, IJ Kobylianskii… - Journal of the …, 2019 - ACS Publications
Carbene polymerization provides polyolefins that cannot be readily prepared from olefin
monomers; however, controlled and living carbene polymerization has been a long-standing …

Polymerization of diazoacetates: New synthetic strategy for CC main chain polymers

E Ihara, H Shimomoto - Polymer, 2019 - Elsevier
Recent progress on polymerization of diazoacetates is described. Polymerization of
diazoacetates has attracted much attention as an efficient method for C1 polymerization …

Polymerization of Diazoacetates Initiated by the Pd(N-arylmaleimide)/NaBPh4 System: Maleimide Insertion into a Pd–C Bond Preceding to Initiation Leading to …

H Shimomoto, H Hayashi, K Aramasu, T Itoh… - …, 2022 - ACS Publications
Three new N-arylmaleimide-based Pd (0) complexes [Pd (N-phenylmaleimide) 2 (2, 5-
norbornadiene)(1), Pd (N-2, 6-difluorophenylmaleimide) 2 (2, 5-norbornadiene)(2), and Pd …

[HTML][HTML] AB5 Derivatives of Cyclotriphosphazene for the Synthesis of Dendrons and Their Applications

A Zibarov, A Oukhrib, J Aujard Catot, CO Turrin… - Molecules, 2021 - mdpi.com
AB5 compounds issued from the reactivity of hexachlorocyclotriphosphazene are relatively
easy to obtain using two ways: either first the reaction of one chloride with one reagent …

C1 polymerization of fluorinated Aryl Diazomethanes

S Kang, SJ Lu, CW Bielawski - ACS Macro Letters, 2021 - ACS Publications
A library of fluorinated aryl diazomethanes were polymerized using BF3· OEt2 as a catalyst.
The polymerization of 2, 3, 4, 5, 6-pentafluorophenyl diazomethane was found to be …

Excited-state dynamics of pyrene incorporated into poly (substituted methylene) s: effects of dense packing of pyrenes on excimer formation

T Takaya, T Oda, Y Shibazaki, Y Hayashi… - …, 2018 - ACS Publications
The excited-state dynamics of pyrene incorporated into poly (substituted methylene) s is
investigated by picosecond time-resolved fluorescence spectroscopy and femtosecond time …