Switchable Fe/Co Prussian blue networks and molecular analogues

D Aguilà, Y Prado, ES Koumousi… - Chemical Society …, 2016 - pubs.rsc.org
With the long term objective to build the next generation of devices from the molecular scale,
scientists have explored extensively in the past two decades the Prussian blue derivatives …

Coupling carbon dioxide reduction with water oxidation in nanoscale photocatalytic assemblies

W Kim, BA McClure, E Edri, H Frei - Chemical Society Reviews, 2016 - pubs.rsc.org
The reduction of carbon dioxide by water with sunlight in an artificial system offers an
opportunity for utilizing non-arable land for generating renewable transportation fuels to …

Metal‐to‐metal electron transfer: a powerful tool for the design of switchable coordination compounds

C Mathonière - European Journal of Inorganic Chemistry, 2018 - Wiley Online Library
Since the report of photomagnetic effects in Prussian blue Fe/Co networks 20 years ago by
the Japanese group of Hashimoto, a substantial family of molecular analogs have been …

The Excited‐State Creutz–Taube Ion

GE Pieslinger, I Ramírez‐Wierzbicki… - Angewandte Chemie …, 2022 - Wiley Online Library
The excited‐state version of the Creutz–Taube ion was prepared via visible light excitation
of [(NH3) 5RuII (μ‐pz) RuII (NH3) 5] 4+. The resulting excited state is a mixed valence {RuIII …

A review of solar and visible light active oxo-bridged materials for energy and environment

L Mohapatra, K Parida - Catalysis Science & Technology, 2017 - pubs.rsc.org
In efficient solar energy conversion for environmental and energy applications, the use of
visible-light-active photocatalysis as a green and sustainable technology has become a …

Ultrafast photoinduced dynamics in Prussian blue analogues

K Barlow, JO Johansson - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
New magnetic materials and methods for controlling them are needed to improve data
storage technologies. Recent progress has enabled optical detection and manipulation of …

Time-resolved spectroscopy of photoinduced electron transfer in dinuclear and tetranuclear Fe/Co Prussian Blue analogues

J Zimara, H Stevens, R Oswald, S Demeshko… - Inorganic …, 2020 - ACS Publications
The dynamics of the photodriven charge transfer-induced spin transition (CTIST) in two
Fe/Co Prussian Blue Analogues (PBAs) are revealed by femtosecond IR and UV/vis pump …

Controlled assembly of hetero-binuclear sites on mesoporous silica: visible light charge-transfer units with selectable redox properties

H Han, H Frei - The Journal of Physical Chemistry C, 2008 - ACS Publications
Mild synthetic methods are demonstrated for the selective assembly of oxo-bridged
heterobinuclear units of the type TiOCrIII, TiOCoII, and TiOCeIII on mesoporous silica …

Directly probing spin dynamics in a molecular magnet with femtosecond time-resolution

JO Johansson, JW Kim, E Allwright, DM Rogers… - Chemical …, 2016 - pubs.rsc.org
We show that a vanadium–chromium Prussian blue analogue, which is a room-temperature
molecule-based magnet, displays a fast magnetic response on a femtosecond timescale that …

Inversion of donor–acceptor roles in photoinduced intervalence charge transfers

BM Aramburu-Trošelj, PS Oviedo… - Chemical …, 2019 - pubs.rsc.org
Upon MLCT photoexcitation,{(tpy) Ru} becomes the electron acceptor in the mixed valence
{(tpy˙−) RuIII− δ-NC-MII+ δ} moiety, reversing its role as the electron donor in the ground …