Alkyl borane-mediated metal-free ring-opening (co) polymerizations of oxygenated monomers
Sensibility to environmental concerns and the actual demand for polymeric materials free of
any metal contaminants in most applications have directed research towards significant …
any metal contaminants in most applications have directed research towards significant …
Progress in the catalytic reactions of CO 2 and epoxides to selectively provide cyclic or polymeric carbonates
GA Bhat, DJ Darensbourg - Green Chemistry, 2022 - pubs.rsc.org
Sustainability requires that we reuse spent carbon sources from CO2 emissions to generate
new products and materials. In this regard, carbon capture is a necessary requirement for …
new products and materials. In this regard, carbon capture is a necessary requirement for …
Sequence control from mixtures: switchable polymerization catalysis and future materials applications
There is an ever-increasing demand for higher-performing polymeric materials
counterbalanced by the need for sustainability throughout the life cycle. Copolymers …
counterbalanced by the need for sustainability throughout the life cycle. Copolymers …
Catalysis as an enabling science for sustainable polymers
The replacement of current petroleum-based plastics with sustainable alternatives is a
crucial but formidable challenge for the modern society. Catalysis presents an enabling tool …
crucial but formidable challenge for the modern society. Catalysis presents an enabling tool …
Understanding metal synergy in heterodinuclear catalysts for the copolymerization of CO2 and epoxides
Carbon dioxide and epoxide copolymerization is an industrially relevant means to valorize
waste and improve sustainability in polymer manufacturing. Given the value of the polymer …
waste and improve sustainability in polymer manufacturing. Given the value of the polymer …
Ring-opening copolymerization of epoxides and cyclic anhydrides with discrete metal complexes: structure–property relationships
JM Longo, MJ Sanford, GW Coates - Chemical reviews, 2016 - ACS Publications
Polyesters synthesized through the alternating copolymerization of epoxides and cyclic
anhydrides compose a growing class of polymers that exhibit an impressive array of …
anhydrides compose a growing class of polymers that exhibit an impressive array of …
Switchable Catalysis Improves the Properties of CO2-Derived Polymers: Poly(cyclohexene carbonate-b-ε-decalactone-b-cyclohexene carbonate) Adhesives …
Carbon dioxide/epoxide copolymerization is an efficient way to add value to waste CO2 and
to reduce pollution in polymer manufacturing. Using this process to make low molar mass …
to reduce pollution in polymer manufacturing. Using this process to make low molar mass …
Recent trends in catalytic polymerizations
DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …
Their popularity has stemmed from their wide range of material properties combined with …
Role of external field in polymerization: mechanism and kinetics
The past decades have witnessed an increasing interest in developing advanced
polymerization techniques subjected to external fields. Various physical modulations, such …
polymerization techniques subjected to external fields. Various physical modulations, such …
Copolymerization of carbon dioxide and epoxides by metal coordination complexes
CM Kozak, K Ambrose, TS Anderson - Coordination Chemistry Reviews, 2018 - Elsevier
The catalytic copolymerization of CO 2 with epoxides to give polycarbonates was discovered
nearly 50 years ago. The last 10 years have been particularly exciting for the development …
nearly 50 years ago. The last 10 years have been particularly exciting for the development …