Fundamentals and Catalytic Applications of CeO2-Based Materials

T Montini, M Melchionna, M Monai… - Chemical …, 2016 - ACS Publications
Cerium dioxide (CeO2, ceria) is becoming an ubiquitous constituent in catalytic systems for
a variety of applications. 2016 sees the 40th anniversary since ceria was first employed by …

The surface chemistry of cerium oxide

DR Mullins - Surface Science Reports, 2015 - Elsevier
This review covers the structure of, and chemical reactions on, well-defined cerium oxide
surfaces. Ceria, or mixed oxides containing ceria, are critical components in automotive …

[HTML][HTML] Creating single-atom Pt-ceria catalysts by surface step decoration

F Dvořák, M Farnesi Camellone, A Tovt… - Nature …, 2016 - nature.com
Single-atom catalysts maximize the utilization of supported precious metals by exposing
every single metal atom to reactants. To avoid sintering and deactivation at realistic reaction …

Oxygen defects and surface chemistry of ceria: quantum chemical studies compared to experiment

J Paier, C Penschke, J Sauer - Chemical reviews, 2013 - ACS Publications
As one of the most significant rare earth oxides, ceria (CeO 2) has attracted much interest
over the past decades. In catalysis, 1, 2 CeO2 serves as a widely used support material and …

Structural and functional insights in polysaccharides coated cerium oxide nanoparticles and their potential biomedical applications: A review

S Yadav, S Chamoli, P Kumar, PK Maurya - International Journal of …, 2023 - Elsevier
Cerium oxide nanoparticles have now significant presence in biomedical fields due to their
wide applications; however, challenges regarding their safety and biocompatibility persist …

Structural motifs of water on metal oxide surfaces

R Mu, Z Zhao, Z Dohnálek, J Gong - Chemical Society Reviews, 2017 - pubs.rsc.org
Understanding water/solid interactions is of great importance in a variety of fundamental and
technological processes, such as photocatalytic water splitting, heterogeneous catalysis …

Importance of the metal–oxide interface in catalysis: In situ studies of the water–gas shift reaction by ambient‐pressure X‐ray photoelectron spectroscopy

K Mudiyanselage, SD Senanayake, L Feria… - Angewandte …, 2013 - Wiley Online Library
The traditional approach to the optimization of metal/oxide catalysts has focused on the
properties of the metal and the selection of the proper oxide for its dispersion. The …

Heterogeneous ceria catalyst with water-tolerant Lewis acidic sites for one-pot synthesis of 1, 3-diols via Prins condensation and hydrolysis reactions

Y Wang, F Wang, Q Song, Q Xin, S Xu… - Journal of the American …, 2013 - ACS Publications
The use of a heterogeneous Lewis acid catalyst, which is insoluble and easily separable
during the reaction, is a promising option for hydrolysis reactions from both environmental …

Enthalpies and entropies of adsorption on well-defined oxide surfaces: Experimental measurements

CT Campbell, JRV Sellers - Chemical reviews, 2013 - ACS Publications
The chemistry of oxide surfaces plays a central role in many current technologies, and
promises to play an ever-increasing role in future technologies. In addition to their …

Water adsorption and its effect on the stability of low index stoichiometric and reduced surfaces of ceria

M Molinari, SC Parker, DC Sayle… - The Journal of Physical …, 2012 - ACS Publications
The influence of water on the redox properties of ceria is pivotal to its widespread
exploitation spanning a variety of applications. Ab initio simulation techniques based on DFT …