50th Anniversary Perspective: Polymer Brushes: Novel Surfaces for Future Materials
Polymer brushes have become a significant focus of polymer research with the need for
straightforward and versatile surface modification. With the development of controlled radical …
straightforward and versatile surface modification. With the development of controlled radical …
Multivalent counterions diminish the lubricity of polyelectrolyte brushes
Polyelectrolyte brushes provide wear protection and lubrication in many technical, medical,
physiological, and biological applications. Wear resistance and low friction are attributed to …
physiological, and biological applications. Wear resistance and low friction are attributed to …
Role of electrostatic interactions in the adsorption of dye molecules by Ti 3 C 2-MXenes
S Lim, JH Kim, H Park, C Kwak, J Yang, J Kim… - RSC …, 2021 - pubs.rsc.org
MXenes, a new class of 2D materials, have recently attracted increasing attention as
promising adsorbents for environmental remediation. It has been previously demonstrated …
promising adsorbents for environmental remediation. It has been previously demonstrated …
Structure of polyelectrolyte brushes in the presence of multivalent counterions
Polyelectrolyte brushes are of great importance to a wide range of fields, ranging from
colloidal stabilization to responsive and tunable materials to lubrication. We synthesized …
colloidal stabilization to responsive and tunable materials to lubrication. We synthesized …
Hydrophilic and Apolar Hydration in Densely Grafted Cationic Brushes and Counterions with Large Mobilities
We employ an all-atom molecular dynamics (MD) simulation framework to unravel water
microstructure and ion properties for cationic [poly (2-(methacryloyloxy) ethyl) …
microstructure and ion properties for cationic [poly (2-(methacryloyloxy) ethyl) …
Structure and functionality of polyelectrolyte brushes: a surface force perspective
The unique functionality of polyelectrolyte brushes depends on several types of specific
interactions, including solvent structure effects, hydrophobic forces, electrostatic interactions …
interactions, including solvent structure effects, hydrophobic forces, electrostatic interactions …
Multivalent ions induce lateral structural inhomogeneities in polyelectrolyte brushes
Subtle details about a polyelectrolyte's surrounding environment can dictate its structural
features and potential applications. Atomic force microscopy (AFM), surface forces …
features and potential applications. Atomic force microscopy (AFM), surface forces …
Hydration lubrication applicable to artificial joints through polyelectrolyte-embedded modification on UHMWPE
J Xu, C Zhang, J Luo - ACS Applied Polymer Materials, 2022 - ACS Publications
Hydration lubrication by the hydrated surface-grafted macromolecules covering the joint
cartilage is crucial for the proper functioning of natural synovial joints. However, when …
cartilage is crucial for the proper functioning of natural synovial joints. However, when …
Unexpected Two-Stage Swelling of Weak Polyelectrolyte Brushes with Divalent Counterions
We use particle-based, coarse-grained simulations to study the influence of divalent
counterions on a weak polyelectrolyte brush. Our simulations show a profound influence of …
counterions on a weak polyelectrolyte brush. Our simulations show a profound influence of …
Jammed polyelectrolyte microgels for 3D cell culture applications: rheological behavior with added salts
The yielding and jamming behaviors of packed granular-scale microgels enable their use as
a support medium for 3D printing stable shapes made from liquid phases; under low levels …
a support medium for 3D printing stable shapes made from liquid phases; under low levels …