Recent advances in 3d-block metal complexes with bi, tri, and tetradentate Schiff base ligands derived from salicylaldehyde and its derivatives: Synthesis …

M Kumar, AK Singh, AK Singh, RK Yadav… - Coordination Chemistry …, 2023 - Elsevier
Schiff bases have been of continued interest in coordination chemistry for a long time
because they provide new ligand platforms that make reactivity easier and their metal …

Multipolar interactions in -electron systems: The paradigm of actinide dioxides

P Santini, S Carretta, G Amoretti, R Caciuffo… - Reviews of Modern …, 2009 - APS
This article reviews the physics of multipolar interactions and multipolar order in f-electron
systems, using the actinide dioxides as a paradigm. In the past few years, these apparently …

A criterion for the anisotropy barrier in single-molecule magnets

O Waldmann - Inorganic chemistry, 2007 - ACS Publications
A criterion for the height of the anisotropy barrier Δ=| D| S 2 in single-molecule magnets, and
therefore the blocking temperature TB∝ Δ, is presented. In particular, it is found that the …

Magnetic cluster excitations

A Furrer, O Waldmann - Reviews of Modern Physics, 2013 - APS
Magnetic clusters, ie, assemblies of a finite number (between two or three and several
hundred) of interacting spin centers which are magnetically decoupled from their …

Disentangling intricate web of interrelated notions at the interface between the physical (crystal field) Hamiltonians and the effective (spin) Hamiltonians

C Rudowicz, M Karbowiak - Coordination Chemistry Reviews, 2015 - Elsevier
This review provides a summary of distinct Hamiltonians used to describe magnetic and
spectroscopic properties of paramagnetic and magnetic coordination compounds. Based on …

Microscopic spin Hamiltonian of a antiferromagnetic ring from inelastic neutron scattering

S Carretta, J Van Slageren, T Guidi, E Liviotti… - Physical Review B, 2003 - APS
Exchange integrals and single-ion anisotropy parameters of a ring-shaped molecular
cluster, comprising eight chromium (III) ions (s= 3/2) were determined by inelastic neutron …

Solvent-induced structural diversity in tetranuclear Ni (ii) Schiff-base complexes: the first Ni 4 single-molecule magnet with a defective dicubane-like topology

R Herchel, I Nemec, M Machata, Z Trávníček - Dalton Transactions, 2016 - pubs.rsc.org
Two tetranuclear NiII complexes, namely [Ni4 (L) 4 (CH3OH) 3 (H2O)]· CH3OH (1) and
(Pr3NH) 2 [Ni4 (L) 4 (CH3COO) 2](2, Pr3N= tripropylamine), were synthesized from a …

Engineering molecular rings for magnetocaloric effect

M Affronte, A Ghirri, S Carretta, G Amoretti… - Applied physics …, 2004 - pubs.aip.org
By substituting one Cr 3+(s= 3/2) with Cd 2+(s= 0) in molecular octanuclear rings, a diluted
ensemble of identical nanomagnets with a S= 3/2 ground state, weakly split in zero field, is …

The origin of transverse anisotropy in axially symmetric single molecule magnets

AL Barra, A Caneschi, A Cornia… - Journal of the …, 2007 - ACS Publications
Single-crystal high-frequency electron paramagnetic resonance spectroscopy has been
employed on a truly axial single molecule magnet of formula [Mn12O12 (t Bu-CH2CO2) 16 …

Spin dynamics of heterometallic wheels (, Zn, Ni) probed by inelastic neutron scattering

R Caciuffo, T Guidi, G Amoretti, S Carretta, E Liviotti… - Physical Review B …, 2005 - APS
Inelastic neutron scattering has been applied to the study of the spin dynamics of Cr-based
antiferromagnetic octanuclear rings where a finite total spin of the ground state is obtained …