NHCs in main group chemistry
V Nesterov, D Reiter, P Bag, P Frisch, R Holzner… - Chemical …, 2018 - ACS Publications
Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …
1990s, these divalent carbon species have become a common and available class of …
N-heterocyclic carbene adducts of main group elements and their use as ligands in transition metal chemistry
N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …
research fields, and it is not possible to imagine modern transition metal and main group …
Preformed molecular complexes of metals with organoselenium ligands: Syntheses and applications in catalysis
Organoselenium compounds have been used extensively as building blocks for the
development of catalysts for several chemical transformations during the last two decades …
development of catalysts for several chemical transformations during the last two decades …
Highly active mesoionic chalcogenone zinc (II) derivatives for C–S cross-coupling reactions
M Vaddamanu, K Velappan… - New Journal of Chemistry, 2020 - pubs.rsc.org
The first mesoionic heavier chalcogenones, L1–L3 [L1= 1-(2-mesitylene)-3-methyl-4-
phenyltriazolin-5-selone; L2= 1-(2-mesitylene)-3-methyl-4-phenyltriazolin-5-thione; L3= 1 …
phenyltriazolin-5-selone; L2= 1-(2-mesitylene)-3-methyl-4-phenyltriazolin-5-thione; L3= 1 …
Recent progress in designing the synthetic strategies for bismuth based complexes
S Andleeb - Journal of Organometallic Chemistry, 2019 - Elsevier
This short review article provides an insight into the synthetic chemistry involved in the
formation of bismuth based versatile frameworks. A unique feature of bismuth compounds is …
formation of bismuth based versatile frameworks. A unique feature of bismuth compounds is …
Recent developments in the chemistry of NHC-based selones: syntheses, applications and reactivity
Selones, since their first report in 1963, have attracted significant interest with respect to their
bonding, structure and more importantly as an ancillary ligand for complexation with various …
bonding, structure and more importantly as an ancillary ligand for complexation with various …
Highly active higher coordinated copper (i)–N-heterocyclic chalcogenone catalysed click chemistry
S Mandal, D Harijan, G Muduli… - New Journal of …, 2023 - pubs.rsc.org
The tri-coordinated and tetra-coordinated copper (I)–N-heterocyclic chalcogenone catalysed
[3+ 2] cycloaddition reaction has been reported to understand the role of ancillary ligands …
[3+ 2] cycloaddition reaction has been reported to understand the role of ancillary ligands …
Synthesis, characterization, and catalytic activities of palladium complexes with phenylene-bridged bis (thione) ligands
WG Jia, LL Gao, ZB Wang, LY Sun, YF Han - Organometallics, 2019 - ACS Publications
The neutral phenylene-bridged bis (thione) compounds, 1, 3-bis (3′-ethylimidazolyl-2′-
thione) benzene (Betb), 1, 3-bis (3′-butylimidazolyl-2′-thione) benzene (Bbtb), and 1, 3 …
thione) benzene (Betb), 1, 3-bis (3′-butylimidazolyl-2′-thione) benzene (Bbtb), and 1, 3 …
Tweaking the charge transfer: bonding analysis of Bismuth (III) complexes with a flexidentate phosphane ligand
R Mokrai, J Barrett, DC Apperley, Z Benkő… - Inorganic …, 2020 - ACS Publications
To account for the charge transfer and covalent character in bonding between P and Bi
centers, the electronic structures of [P (C6H4-o-CH2SCH3) 3BiCl n](3–n)+(n= 0–3) model …
centers, the electronic structures of [P (C6H4-o-CH2SCH3) 3BiCl n](3–n)+(n= 0–3) model …
Role of C, S, Se and P donor ligands in copper (I) mediated C–N and C–Si bond formation reactions
K Srinivas, G Prabusankar - RSC advances, 2018 - pubs.rsc.org
The first comparative study of C, S, Se and P donor ligands-supported copper (I) complexes
for C–N and C–Si bond formation reactions are described. The syntheses and …
for C–N and C–Si bond formation reactions are described. The syntheses and …