NHCs in main group chemistry

V Nesterov, D Reiter, P Bag, P Frisch, R Holzner… - Chemical …, 2018 - ACS Publications
Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …

N-heterocyclic carbene adducts of main group elements and their use as ligands in transition metal chemistry

A Doddi, M Peters, M Tamm - Chemical reviews, 2019 - ACS Publications
N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …

Preformed molecular complexes of metals with organoselenium ligands: Syntheses and applications in catalysis

A Arora, S Singh, P Oswal, D Nautiyal, GK Rao… - Coordination Chemistry …, 2021 - Elsevier
Organoselenium compounds have been used extensively as building blocks for the
development of catalysts for several chemical transformations during the last two decades …

Highly active mesoionic chalcogenone zinc (II) derivatives for C–S cross-coupling reactions

M Vaddamanu, K Velappan… - New Journal of Chemistry, 2020 - pubs.rsc.org
The first mesoionic heavier chalcogenones, L1–L3 [L1= 1-(2-mesitylene)-3-methyl-4-
phenyltriazolin-5-selone; L2= 1-(2-mesitylene)-3-methyl-4-phenyltriazolin-5-thione; L3= 1 …

Recent progress in designing the synthetic strategies for bismuth based complexes

S Andleeb - Journal of Organometallic Chemistry, 2019 - Elsevier
This short review article provides an insight into the synthetic chemistry involved in the
formation of bismuth based versatile frameworks. A unique feature of bismuth compounds is …

Recent developments in the chemistry of NHC-based selones: syntheses, applications and reactivity

S Yadav, R Deka, HB Singh - Chemistry Letters, 2019 - academic.oup.com
Selones, since their first report in 1963, have attracted significant interest with respect to their
bonding, structure and more importantly as an ancillary ligand for complexation with various …

Highly active higher coordinated copper (i)–N-heterocyclic chalcogenone catalysed click chemistry

S Mandal, D Harijan, G Muduli… - New Journal of …, 2023 - pubs.rsc.org
The tri-coordinated and tetra-coordinated copper (I)–N-heterocyclic chalcogenone catalysed
[3+ 2] cycloaddition reaction has been reported to understand the role of ancillary ligands …

Synthesis, characterization, and catalytic activities of palladium complexes with phenylene-bridged bis (thione) ligands

WG Jia, LL Gao, ZB Wang, LY Sun, YF Han - Organometallics, 2019 - ACS Publications
The neutral phenylene-bridged bis (thione) compounds, 1, 3-bis (3′-ethylimidazolyl-2′-
thione) benzene (Betb), 1, 3-bis (3′-butylimidazolyl-2′-thione) benzene (Bbtb), and 1, 3 …

Tweaking the charge transfer: bonding analysis of Bismuth (III) complexes with a flexidentate phosphane ligand

R Mokrai, J Barrett, DC Apperley, Z Benkő… - Inorganic …, 2020 - ACS Publications
To account for the charge transfer and covalent character in bonding between P and Bi
centers, the electronic structures of [P (C6H4-o-CH2SCH3) 3BiCl n](3–n)+(n= 0–3) model …

Role of C, S, Se and P donor ligands in copper (I) mediated C–N and C–Si bond formation reactions

K Srinivas, G Prabusankar - RSC advances, 2018 - pubs.rsc.org
The first comparative study of C, S, Se and P donor ligands-supported copper (I) complexes
for C–N and C–Si bond formation reactions are described. The syntheses and …