Recent progress in solid‐state nuclear magnetic resonance of half‐integer spin low‐γ quadrupolar nuclei applied to inorganic materials
ME Smith - Magnetic Resonance in Chemistry, 2021 - Wiley Online Library
An overview is presented of recent progress in the solid‐state nuclear magnetic resonance
(NMR) observation of low‐γ nuclei, with a focus on applications to inorganic materials. The …
(NMR) observation of low‐γ nuclei, with a focus on applications to inorganic materials. The …
Compositional dependence of solubility/retention of molybdenum oxides in aluminoborosilicate-based model nuclear waste glasses
Molybdenum oxides are an integral component of the high-level waste streams being
generated from the nuclear reactors in several countries. Although borosilicate glass has …
generated from the nuclear reactors in several countries. Although borosilicate glass has …
Impacts of substitution of Fe2O3 for SiO2 on structure and properties of borosilicate glasses containing MoO3
Y Xu, Q Liao, F Wang, H Zhu, Z He, M Fu… - Journal of Non-Crystalline …, 2023 - Elsevier
Borosilicate glass is an effective matrix for vitrification of high-level nuclear waste. However,
the solubility of molybdenum is lower. In this paper, the impacts of Fe 2 O 3 replacing SiO 2 …
the solubility of molybdenum is lower. In this paper, the impacts of Fe 2 O 3 replacing SiO 2 …
Improving molybdenum and sulfur vitrification in borosilicate nuclear waste glasses using phosphorus: structural insights from NMR
A Krishnamurthy, S Kroeker - Inorganic chemistry, 2021 - ACS Publications
Reclaiming residual fissile materials from spent nuclear fuel rods results in highly
radioactive waste that must be immobilized in durable materials to protect the biosphere …
radioactive waste that must be immobilized in durable materials to protect the biosphere …
Examining phase separation and crystallization in glasses with X-ray nano-computed tomography
X-ray nano-computed tomography (nano-CT) is a powerful technique to characterize and
visualize 3 dimensional (3D) phenomena in complex glasses at the nanoscale. This …
visualize 3 dimensional (3D) phenomena in complex glasses at the nanoscale. This …
Rheology of a sodium‐molybdenum borosilicate melt undergoing phase separation
During glass production, phase separation can result in the formation of suspended liquid
droplets, which can cause changes in the system rheology. In nuclear waste vitrification …
droplets, which can cause changes in the system rheology. In nuclear waste vitrification …
Crystallization of Cristobalite in Sodium Borosilicate Glass in the Presence of Cr2O3
M Konon, IG Polyakova, AS Mazur, AS Saratovskii… - Materials, 2023 - mdpi.com
Glass containing chromium is a promising material for use in various modern fields of
application (laser technology, optoelectronic devices, and luminescent resources) …
application (laser technology, optoelectronic devices, and luminescent resources) …
Dismantling nuclear waste rich in P2O5, MoO3 and ZrO2: How do these oxides incorporate in aluminoborosilicate glasses?
Dismantling nuclear facilities leads to radioactive waste less active but which may have
highly variable compositions compared to the high-level radioactive wastes recovered after …
highly variable compositions compared to the high-level radioactive wastes recovered after …
Network structure and dissolution properties of phosphate-doped borosilicate glasses
The addition of phosphorus to conventional borosilicate glasses is explored as a way to
increase the incorporation of high-field-strength cations such as Mo (VI) into chemically …
increase the incorporation of high-field-strength cations such as Mo (VI) into chemically …
Rare-earth silicate crystallization in borosilicate glasses: Effect on structural and chemical durability properties
E Nicoleau, F Angeli, S Schuller, T Charpentier… - Journal of Non …, 2016 - Elsevier
Due to their low solubility, some elements, such as lanthanides, can lead to crystalline
phases in borosilicate glass during cooling. The impact of rare earth (lanthanum and …
phases in borosilicate glass during cooling. The impact of rare earth (lanthanum and …