Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Metal sites in zeolites: synthesis, characterization, and catalysis

Q Zhang, S Gao, J Yu - Chemical reviews, 2022 - ACS Publications
Zeolites with ordered microporous systems, distinct framework topologies, good spatial
nanoconfinement effects, and superior (hydro) thermal stability are an ideal scaffold for …

Catalytic deconstruction of waste polyethylene with ethylene to form propylene

RJ Conk, S Hanna, JX Shi, J Yang, NR Ciccia, L Qi… - Science, 2022 - science.org
The conversion of polyolefins to monomers would create a valuable carbon feedstock from
the largest fraction of waste plastic. However, breakdown of the main chains in these …

Dealuminated Beta zeolite reverses Ostwald ripening for durable copper nanoparticle catalysts

L Liu, J Lu, Y Yang, W Ruettinger, X Gao, M Wang… - Science, 2024 - science.org
Copper nanoparticle–based catalysts have been extensively applied in industry, but the
nanoparticles tend to sinter into larger ones in the chemical atmospheres, which is …

Design strategies of stable catalysts for propane dehydrogenation to propylene

ML Sun, ZP Hu, HY Wang, YJ Suo, ZY Yuan - ACS Catalysis, 2023 - ACS Publications
Propylene is one of the most important building blocks for the chemical industry. Traditional
propylene production, which is based on oil-based cracking processes, is being challenged …

Confining platinum clusters in indium-modified ZSM-5 zeolite to promote propane dehydrogenation

Y Yuan, E Huang, S Hwang, P Liu, JG Chen - Nature Communications, 2024 - nature.com
Designing highly active and stable catalytic sites is often challenging due to the complex
synthesis procedure and the agglomeration of active sites during high-temperature …

Negatively Charged Single-Atom Pt Catalyst Shows Superior SO2 Tolerance in NOx Reduction by CO

Y Ji, S Liu, S Song, W Xu, L Li, Y Zhang, W Chen… - ACS …, 2022 - ACS Publications
Pt-based catalysts are promising for the selective catalytic reduction of NO x by CO (CO-
SCR), but some technical issues hinder their practical application, including the high Pt …

Recent progress in metal-molecular sieve catalysts for propane dehydrogenation

S Song, Y Sun, K Yang, Y Fo, X Ji, H Su, Z Li, C Xu… - ACS …, 2023 - ACS Publications
Propane direct dehydrogenation (PDH) is an attractive technology for propylene production
that has received extensive attention. Molecular sieves with uniform porous structure, high …

High-entropy intermetallics serve ultrastable single-atom Pt for propane dehydrogenation

Y Nakaya, E Hayashida, H Asakura… - Journal of the …, 2022 - ACS Publications
Propane dehydrogenation has been a promising propylene production process that can
compensate for the increasing global demand for propylene. However, Pt-based catalysts …

A Robust and Efficient Propane Dehydrogenation Catalyst from Unexpectedly Segregated Pt2Mn Nanoparticles

L Rochlitz, Q Pessemesse, JWA Fischer… - Journal of the …, 2022 - ACS Publications
The increasing demand for short chain olefins like propene for plastics production and the
availability of shale gas make the development of highly performing propane …