Replacement strategies for non-green dipolar aprotic solvents
Dipolar aprotic solvents (DMSO, DMF, DMAc, NMP, etc.) have been widely used in organic
synthesis and pharmaceutical research because of their remarkable polarities and …
synthesis and pharmaceutical research because of their remarkable polarities and …
Development of the applications of palladium on charcoal in organic synthesis
Palladium on charcoal (Pd/C) has lots of salient merits:(i) it is a cheap and commercial
source of palladium,(ii) it shows efficient catalytic activity even without ligands,(iii) as a …
source of palladium,(ii) it shows efficient catalytic activity even without ligands,(iii) as a …
Environmentally Friendly, Co-catalyst-Free Chemical Fixation of CO2 at Mild Conditions Using Dual-Walled Nitrogen-Rich Three-Dimensional Porous Metal–Organic …
Highly porous, polyhedral metal–organic frameworks (MOFs) of Co (II)/Ni (II),{[M6 (TATAB) 4
(DABCO) 3 (H2O) 3]· 12DMF· 9H2O} n (where M= Co (II)(1)/Ni (II)(2), H3TATAB= 4, 4′, 4 …
(DABCO) 3 (H2O) 3]· 12DMF· 9H2O} n (where M= Co (II)(1)/Ni (II)(2), H3TATAB= 4, 4′, 4 …
A novel zirconium-based metal–organic framework covalently modified by methyl pyridinium bromide for mild and co-catalyst free conversion of CO 2 to cyclic …
JH Xu, SF Peng, YK Shi, S Ding, GS Yang… - Dalton …, 2023 - pubs.rsc.org
Building metal–organic frameworks (MOFs) covalently modified by onium halides is a
promising approach to develop efficient MOF-based heterogeneous catalysts for the …
promising approach to develop efficient MOF-based heterogeneous catalysts for the …
Chemical Fixation of CO2 Under Solvent and Co-Catalyst-free Conditions Using a Highly Porous Two-fold Interpenetrated Cu(II)-Metal–Organic Framework
A highly porous metal–organic framework (MOF) based on the Cu (II) ion,{[Cu6 (TATAB) 4
(DABCO) 3 (H2O) 3]· 24DMF} n (Cu (II)-MOF)(where H3TATAB= 4, 4′, 4 ″-s-triazine-1, 3, 5 …
(DABCO) 3 (H2O) 3]· 24DMF} n (Cu (II)-MOF)(where H3TATAB= 4, 4′, 4 ″-s-triazine-1, 3, 5 …
Pd-Catalyzed Perfluoroalkylative Aryloxycarbonylation of Alkynes with Formates as CO Surrogates
B Gatlik, W Chaładaj - ACS Catalysis, 2021 - ACS Publications
The highly toxic, inflammable, and odorless nature of CO causes problematic handling on
laboratory-scale experiments. Replacement of CO cylinders by CO surrogates is particularly …
laboratory-scale experiments. Replacement of CO cylinders by CO surrogates is particularly …
Carbonylative Tertiary Amide Synthesis from Aryl Iodides and Tertiary Amines via Oxidant‐Free C−N Bond Cleavage Catalyzed by Palladium(II) Chloride in …
RS Mane, BM Bhanage - Advanced Synthesis & Catalysis, 2017 - Wiley Online Library
In this work, we have described the carbonylative synthesis of amides from aryl iodides and
tertiary amines as an aminal source via oxidant‐free C (sp3)− N bond cleavage using in situ …
tertiary amines as an aminal source via oxidant‐free C (sp3)− N bond cleavage using in situ …
Palladium(II)/N-Heterocyclic Carbene-Catalyzed Direct C–H Acylation of Heteroarenes with N-Acylsaccharins
S Karthik, T Gandhi - Organic letters, 2017 - ACS Publications
N-Acylsaccharin represents a facile acyl group transfer agent to heteroarenes in the
presence of Pd (II)/NHC complexes appended with a pyrene unit. Catalytic acylation of …
presence of Pd (II)/NHC complexes appended with a pyrene unit. Catalytic acylation of …
Supported Palladium Catalyzed Carbonylative Coupling Reactions using Carbon Monoxide as C1 Source
The carbonylative reactions of aryl halides, boronic acids, amines, activated alkene and
alkynes under CO and supported palladium catalyzed conditions are very popular reactions …
alkynes under CO and supported palladium catalyzed conditions are very popular reactions …
Cu@UgC3N4 Catalyzed Cyclization of o-Phenylenediamines for the Synthesis of Benzimidazoles by Using CO2 and Dimethylamine Borane as a Hydrogen …
VV Phatake, BM Bhanage - Catalysis Letters, 2019 - Springer
This work reports a green and sustainable route for the synthesis of benzimidazoles via C–N
bond formation using carbon dioxide (CO 2) as a C 1 carbon source. In this work, Cu@ UgC …
bond formation using carbon dioxide (CO 2) as a C 1 carbon source. In this work, Cu@ UgC …