Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …

This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

Over the past few years, CuH‐catalyzed hydroamination has been discovered and
developed as a robust and conceptually novel approach for the synthesis of …

We report a practical method for the alkylation of N–H bonds with alkanes using a
photoinduced copper (II) peroxide catalytic system. Upon light irradiation, the peroxide …

The development of a mild and general method for the alkylation of amides with relatively
unreactive alkyl halides (ie, poor substrates for SN2 reactions) is an ongoing challenge in …

Developing earth-abundant, non-platinum metal catalysts for high-value chemical
transformations is a critical challenge to contemporary chemical synthesis. Dearomatization …

Using a single half-sandwich iron (II) compound, Cp* Fe (1, 2-Ph2PC6H4S)(NCMe)(Cp*–=
C5Me5–, 1) as a catalyst, reductive coupling of nitroarenes with olefins has been achieved …

In this chapter we review mechanistic concepts of carbon–heteroatom bond formation
involving hydrofunctionalization of double and triple carbon–carbon bonds via migratory …

The development of an anti-Markovnikov-selective hydroamination of unactivated alkenes is
a significant challenge in organometallic chemistry. Herein, we present the rhodium …

An efficient and selective bis (amidate) bis (amido) titanium precatalyst for the anti-
Markovnikov hydroamination of alkynes is reported. Hydroamination of terminal and internal …