Biobased vitrimers: Towards sustainable and adaptable performing polymer materials
In the last decades, Covalent Adaptable Networks (CAN) appeared as an innovative
polymer family, able to bridge the gap between thermoplastics and thermosets. CAN rely on …
polymer family, able to bridge the gap between thermoplastics and thermosets. CAN rely on …
Vitrimers: Current research trends and their emerging applications
The development of recyclable plastics is a key research focus in today's world due to their
environmental issues, and non-renewability concerns. Recently, vitrimeric materials have …
environmental issues, and non-renewability concerns. Recently, vitrimeric materials have …
Vitrimers: directing chemical reactivity to control material properties
The development of more sustainable materials with a prolonged useful lifetime is a key
requirement for a transition towards a more circular economy. However, polymer materials …
requirement for a transition towards a more circular economy. However, polymer materials …
Fast dynamic siloxane exchange mechanism for reshapable vitrimer composites
T Debsharma, V Amfilochiou… - Journal of the …, 2022 - ACS Publications
To develop siloxane-containing vitrimers with fast dynamic characteristics, different
mechanistic pathways have been investigated using a range of catalysts. In particular, one …
mechanistic pathways have been investigated using a range of catalysts. In particular, one …
Vitrimer composites: current status and future challenges
V Schenk, K Labastie, M Destarac, P Olivier… - Materials …, 2022 - pubs.rsc.org
Thermosets dominate the composite industry owing to their outstanding stiffness to weight
ratio and fatigue resistance. Nevertheless, the possibilities of recycling these materials are …
ratio and fatigue resistance. Nevertheless, the possibilities of recycling these materials are …
Neighboring group participation and internal catalysis effects on exchangeable covalent bonds: application to the thriving field of vitrimer chemistry
F Cuminet, S Caillol, É Dantras, E Leclerc… - …, 2021 - ACS Publications
Vitrimers constitute a fascinating class of polymer materials that make the link between the
historically opposed 3D networks (thermosets) and linear polymers (thermoplastics). Their …
historically opposed 3D networks (thermosets) and linear polymers (thermoplastics). Their …
Multiple H‐Bonding Cross‐Linked Supramolecular Solid–Solid Phase Change Materials for Thermal Energy Storage and Management
C Wang, X Geng, J Chen, H Wang, Z Wei… - Advanced …, 2024 - Wiley Online Library
Solid–solid phase change materials (SSPCMs) are considered among the most promising
candidates for thermal energy storage and management. However, the application of …
candidates for thermal energy storage and management. However, the application of …
Suppressing creep and promoting fast reprocessing of vitrimers with reversibly trapped amines
F Van Lijsebetten, K De Bruycker… - Angewandte Chemie …, 2022 - Wiley Online Library
We report a straightforward chemical strategy to tackle current challenges of irreversible
deformation in low Tg vitrimers at operating temperature. In particular, vinylogous urethane …
deformation in low Tg vitrimers at operating temperature. In particular, vinylogous urethane …
Rheological properties of covalent adaptable networks with 1, 2, 3-triazolium cross-links: the missing link between vitrimers and dissociative networks
A Jourdain, R Asbai, O Anaya, MM Chehimi… - …, 2020 - ACS Publications
Vitrimers, in stringent contrast to dissociative networks, involve associative covalent
exchanges and remain fully cross-linked at all temperatures. However, we have previously …
exchanges and remain fully cross-linked at all temperatures. However, we have previously …
Fast reprocessing of acetal covalent adaptable networks with high performance enabled by neighboring group participation
Q Li, S Ma, P Li, B Wang, Z Yu, H Feng, Y Liu… - …, 2021 - ACS Publications
Covalent adaptable networks (CANs) represent a transition material combining favorable
features of thermosets and thermoplastics. However, it is still a huge challenge to …
features of thermosets and thermoplastics. However, it is still a huge challenge to …