Asymmetric catalysis with transition‐metal complexes is the basis for a vast array of
stereoselective transformations and has changed the face of modern synthetic chemistry …

In the past decades there has been a dramatic increase in the demand for enantiopure
compounds for fine-chemicals (ie, agrochemicals and pharmaceuticals) and material …

The conjugate addition of carbon nucleophiles to acceptor activated olefins is one of the
most important reactions for carbon-carbon bond formation. With optically active metal …

We describe a general catalytic methodology for the enantioselective dearomative alkylation
of pyridine derivatives with Grignard reagents, allowing direct access to nearly enantiopure …

Among many other strategies, the enaminone approach is an important strategy to construct
and diversify the azacyclic core in various alkaloids syntheses. In this brief review we …

Die asymmetrische Katalyse mit Übergangsmetallkomplexen ist die Grundlage unzähliger
stereoselektiver Umwandlungen und hat damit das Bild der modernen Synthesechemie …

This review comprises two major parts, which have chiral metal enolates as their focus. In
the first part, we discuss transition-metal-catalyzed conjugate additions leading to chiral …

Stable and reusable tetraorganosilicon reagents, alkenyl-, aryl-, and silyl [2-(hydroxymethyl)
phenyl] dimethylsilanes, undergo 1, 4-addition reactions to α, β-unsaturated carbonyl …

Chiral complexes of [Pd (S, S-chiraphos)(PhCN) 2](SbF6) 2 (2b) and [Pd (S, S-
dipamp)(PhCN) 2](SbF6) 2 (2c) catalyzed the highly enantioselective 1, 4-additions of …

Ten types of new P-chiral phosphorodiamidite ligands having pyrrolo [1, 2-c][1, 3, 2]
diazaphosphol-1-one backbone were designed and prepared. They were preliminarily …