Switching in metal–organic frameworks
In recent years, metal–organic frameworks (MOFs) have become an area of intense
research interest because of their adjustable pores and nearly limitless structural diversity …
research interest because of their adjustable pores and nearly limitless structural diversity …
The story of the little blue box: a tribute to Siegfried Hünig
The tetracationic cyclophane, cyclobis (paraquat‐p‐phenylene), also known as the little blue
box, constitutes a modular receptor that has facilitated the discovery of many host–guest …
box, constitutes a modular receptor that has facilitated the discovery of many host–guest …
Radical-pairing-induced molecular assembly and motion
Radical-pairing interactions between conjugated organic π-radicals are relative newcomers
to the inventory of molecular recognition motifs explored in supramolecular chemistry. The …
to the inventory of molecular recognition motifs explored in supramolecular chemistry. The …
Wholly synthetic molecular machines
C Cheng, JF Stoddart - ChemPhysChem, 2016 - Wiley Online Library
The past quarter of a century has witnessed an increasing engagement on the part of
physicists and chemists in the design and synthesis of molecular machines de novo. This …
physicists and chemists in the design and synthesis of molecular machines de novo. This …
Introducing stable radicals into molecular machines
Y Wang, M Frasconi, JF Stoddart - ACS Central Science, 2017 - ACS Publications
Ever since their discovery, stable organic radicals have received considerable attention from
chemists because of their unique optical, electronic, and magnetic properties. Currently, one …
chemists because of their unique optical, electronic, and magnetic properties. Currently, one …
Ruthenium tris (bipyridine) complexes: Interchange between photons and electrons in molecular-scale devices and machines
This review deals with a very peculiar molecule,[Ru (bpy) 3] 2+(bpy: 2, 2′-bipyridine), and
its interaction with photons and electrons. We summarize the properties that make [Ru (bpy) …
its interaction with photons and electrons. We summarize the properties that make [Ru (bpy) …
Complete mechanism of hemithioindigo motor rotation
R Wilcken, M Schildhauer, F Rott… - Journal of the …, 2018 - ACS Publications
Hemithioindigo-based molecular motors are powered by nondamaging visible light and
provide very fast directional rotations at ambient conditions. Their ground state energy …
provide very fast directional rotations at ambient conditions. Their ground state energy …
An electrochromic tristable molecular switch
A tristable [2] catenane, composed of a macrocyclic polyether incorporating 1, 5-
dioxynaphthalene (DNP) and tetrathiafulvalene (TTF) units along with a 4, 4′-bipyridinium …
dioxynaphthalene (DNP) and tetrathiafulvalene (TTF) units along with a 4, 4′-bipyridinium …
Photochromic and nonphotochromic luminescent supramolecular isomers based on carboxylate-functionalized bipyridinium ligand:(4, 4)-net versus interpenetrated (6 …
J Wang, SL Li, XM Zhang - ACS Applied Materials & Interfaces, 2016 - ACS Publications
Photochromic and nonphotochromic luminescent bipyridinium-based supramolecular
isomers [Cd (CPBPY)(BDC)(H2O)] n (1) and {[Cd (CPBPY)(BDC)]· H2O} n (2)(CPBPY= N-(3 …
isomers [Cd (CPBPY)(BDC)(H2O)] n (1) and {[Cd (CPBPY)(BDC)]· H2O} n (2)(CPBPY= N-(3 …
The roles of intrinsic barriers and crystal fluidity in determining the dynamics of crystalline molecular rotors and molecular machines
ME Howe, MA Garcia-Garibay - The Journal of Organic Chemistry, 2019 - ACS Publications
Crystalline solids are a promising platform for the development of molecular machines. They
have the potential of combining the molecular-level control of physical properties caused by …
have the potential of combining the molecular-level control of physical properties caused by …