[HTML][HTML] Tailoring gold nanocluster properties for biomedical applications: from sensing to bioimaging and theranostics
Gold nanomaterials have emerged as versatile systems which hold a great promise for
several biomedical applications. Among them, gold nanoclusters (AuNCs), ultra-small …
several biomedical applications. Among them, gold nanoclusters (AuNCs), ultra-small …
N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters
EL Albright, TI Levchenko, VK Kulkarni… - Journal of the …, 2024 - ACS Publications
This perspective highlights advances in the preparation and understanding of metal
nanoclusters stabilized by organic ligands with a focus on N-heterocyclic carbenes (NHCs) …
nanoclusters stabilized by organic ligands with a focus on N-heterocyclic carbenes (NHCs) …
Enantiopure Chiral Au13 Nanoclusters Stabilized by Ditopic N-Heterocyclic Carbenes: Synthesis, Characterization, and Electrocatalytic Reduction of CO2
EL Albright, S Malola, SI Jacob, H Yi… - Chemistry of …, 2024 - ACS Publications
A series of chiral Au13 nanoclusters were synthesized via the direct reduction of chiral
dinuclear Au (I) halide complexes ligated by chiral dioxalone-linked bis-N-heterocyclic …
dinuclear Au (I) halide complexes ligated by chiral dioxalone-linked bis-N-heterocyclic …
Gold(I)‐N‐Heterocyclic Carbene Synthons in Organometallic Synthesis
T Scattolin, G Tonon, E Botter, SG Guillet… - … A European Journal, 2023 - Wiley Online Library
The prominent role of gold‐N‐heterocyclic carbene (NHC) complexes in numerous research
areas such as homogeneous (photo) catalysis, medicinal chemistry and materials science …
areas such as homogeneous (photo) catalysis, medicinal chemistry and materials science …
Thermal Stability and Electronic Properties of N-Heterocyclic Carbene-Protected Au13 Nanocluster and Phosphine-Protected Analogues
Despite significant advances in manufacturing atomically precise gold nanoclusters
protected by various ligands, there is a limited understanding of the thermal stability …
protected by various ligands, there is a limited understanding of the thermal stability …
Reversible Luminochromism of an N‐Heterocyclic Carbene‐Protected Carbon‐Centered Hexagold(I) Cluster by Solvent and Mechanical Stimuli
Luminochromic gold clusters have potential applications in sensing due to the unique
optical properties arising from their geometric and electronic structures. However, the …
optical properties arising from their geometric and electronic structures. However, the …
[HTML][HTML] Monoarsine-protected icosahedral cluster [Au 13 (AsPh 3) 8 Cl 4]+: comparative studies on ligand effect and surface reactivity with its stibine analogue
JH Yu, ZR Yuan, J Xu, JG Wang, M Azam, TD Li… - Chemical …, 2023 - pubs.rsc.org
Ligand shells of gold nanoclusters play important roles in regulating their molecular and
electronic structures. However, the similar but distinct impacts of the homologous analogues …
electronic structures. However, the similar but distinct impacts of the homologous analogues …
Superatomic Aromaticity in Cyclic Superatomic Molecules: Ligand-Protected Penta-Icosahedral [M@Au11]5 (M = Au, Pt) Clusters
J Gao, Y Zhou, C Xu, L Cheng - The Journal of Physical Chemistry …, 2024 - ACS Publications
Pure or doped gold icosahedra, which can be generally viewed as superatoms, are
promising candidates for cluster-assembled structures. As the first large-scale ring-like gold …
promising candidates for cluster-assembled structures. As the first large-scale ring-like gold …
Reactivity Studies of Cyclic Alkyl (Amino) Carbene (cAAC)‐Supported Phosphinidenide with AuCl
E Nag, M Francis, S Roy - European Journal of Inorganic …, 2024 - Wiley Online Library
A neutral octa‐nuclear AuI‐cluster (2) with molecular formula [(Cy‐cAACPAu) 4 (AuCl) 4][Cy‐
cAAC=: C (N‐2, 6‐iPr2C6H3)(C6H10)(CMe2)(CH2)] has been isolated, and structurally …
cAAC=: C (N‐2, 6‐iPr2C6H3)(C6H10)(CMe2)(CH2)] has been isolated, and structurally …